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Silane oligomer in epoxy molding compound

机译:环氧模塑化合物中的硅烷低聚物

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摘要

With the rapid development of semiconductor packages, the reliability requirement of the epoxy molding compound as the packaging material becomes more and more rigorous. Introducing adhesion prompter is one of the key methods to increase the reliability of epoxy molding compound, and silane coupling agent with different functional group was one of the most common choice of researchers. Compared to common silane, silane oligomer was partially hydrolyzed and contain more condensed functional groups, it might be a good promising candidate of adhesion promoter. Here, we tried silane oligomer as adhesion promoter to replace the silane in epoxy molding compound, and the properties of resulting epoxy molding compound with silane oligomers in have been tested. The results showed that compared to normal silane, silane oligomer accelerated the reaction speed of epoxy molding compound and the gel time (GT) and spiral flow (SF) all were shorten with the silane oligomer in. Epoxy molding compound with mercapto group silane oligomer A and amino group silane oligomer B all disclosed similar water absorption compared to that with normal silane in, while epoxy molding compound with epoxy group silane oligomer C in exhibited about 25% higher than that with normal silane in. Adhesion test revealed that epoxy molding compound with silane oligomer in all possessed higher adhesion on NiPaAu (PPF) leadframes with the value above 100 N after MSL3 test.
机译:随着半导体封装的快速发展,环氧模塑化合物作为包装材料的可靠性要求变得越来越严格。引入粘附PROMPTER是提高环氧模塑化合物可靠性的关键方法之一,硅烷偶联剂具有不同官能团的研究人员最常见的选择之一。与常见的硅烷相比,硅烷低聚物部分水解并含有更稠合的官能团,这可能是粘合促进剂的良好有希望的候选剂。这里,我们尝试了硅烷低聚物作为粘合促进剂,以替代环氧模塑化合物中的硅烷,并测试了与硅烷低聚物的环氧模塑化合物的性质进行了测试。结果表明,与正常硅烷相比,硅烷低聚物加速了环氧模塑化合物的反应速度,凝胶时间(GT)和螺旋流动(SF)均用硅烷低聚物缩短。环氧模塑化合物与巯基硅烷铝烷寡聚体A.与氨基甲烷寡聚物B相比,与正常硅烷相比,氨基组硅烷低聚物B均公开了类似的吸水性,而具有环氧基硅烷寡聚体C的环氧模塑化合物表现出约25℃的含量高于正常硅烷。粘合试验显示环氧模塑化合物在MSL3试验后,硅烷低聚物在所有在NIPAAU(PPF)引线帧上具有更高的粘附性,具有高于100n的值。

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