Preparation and Performance of Cerium Dioxide Film by Anodization and Heat Treating

摘要

The cerium dioxide films were prepared with cerium foils as raw materials by anodization and heat treating method. The anodic cerium oxide films were heat treated at 120°C, 220°C and 320°C respectively. The cerium dioxide films were characterized with X-ray diffraction (XRD), energydispersive analyses of X-ray (EDAX), Fourier transform infrared (FTIR) techniques and scanning electron microcopy (SEM), respectively. The anodic cerium oxide film is composed of Ce(OH)₃, CeO₂, Ce₂O₃, and Ce. As the anodic cerium oxide films were heat treated at 120 °C and 220 °C respectively, Ce(OH)₃ and Ce in the anodic cerium oxide films may be converted to Ce₂O₃ or CeO₂, and the heat treated films are composed of Ce₂O₃ and CeO₂ respectively. As the anodic cerium oxide film was heat treated at 320°C, Ce(OH)₃, Ce₂O₃ and Ce in the anodic cerium oxide film may be converted to CeO₂. The heat treated anodic cerium oxide film at 320°C is the cerium dioxide film. The cerium dioxide film has strong absorption in the range of 1600~4000cm-1. The structure of the cerium dioxide film is the porous above and the dense layer below.