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Biomass Based Carbon Nanospheres As Electrode Materials in Lithium Ion Batteries

机译:基于生物质的碳纳米球作为锂离子电池中的电极材料

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Carbon nanospheres (CNSs) are classified as nanostructure carbon materials next to Fullerenes and Carbon Nanotubes and have shown good prospects for application as alternative anodes for Lithium Ion Battery (LIB). CNSs possess some remarkable characteristics such as high specific capacity and good rate capability as anode materials in LIB. In this work, the synthesis of carbon nano-spheres onto the surface of activated carbon support was carried out by thermal assisted catalytic pyrolysis technique and utilizing palm oil as renewable and eco-friendly carbon source. The structure and morphology of the resulting nano carbons are examined with X-ray powder diffraction (XRD) and transmission electron microscopy (TEM). Cyclic voltammetry (CV) and cyclic test of the carbon product as an anode material for lithium ion batteries are also investigated. From TEM observations, it can be shown that CNSs has turbostratic structure in the presence of Fe-metal catalyst. The CNSs have a stable cycle performance up to 100 cycles at a constant current density of 200 mA/g, showing its potential as an anode material in lithium-ion batteries.
机译:碳纳米球(CNS)被列为仅次于富勒烯和碳纳米管的纳米结构碳材料,并已显示出作为锂离子电池(LIB)替代阳极的良好前景。 CNS具有作为LIB中阳极材料的一些显着特征,例如高比容量和良好的倍率能力。在这项工作中,通过热辅助催化热解技术并利用棕榈油作为可再生和环保的碳源,在活性炭载体表面上进行了碳纳米球的合成。用X射线粉末衍射(XRD)和透射电子显微镜(TEM)检查所得纳米碳的结构和形态。还研究了循环伏安法(CV)和作为锂离子电池负极材料的碳产物的循环测试。从TEM观察可知,在Fe-金属催化剂存在下,CNS具有涡轮层状结构。在200 mA / g的恒定电流密度下,CNS具有高达100个循环的稳定循环性能,显示了其作为锂离子电池负极材料的潜力。

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