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Type Ⅱ Hot Corrosion Behaviors of Cr, Al, C Binary and Ternary Thin Film Coatings on Ni-201

机译:Ni-201上Cr,Al,C二元和三元薄膜涂层的Ⅱ型热腐蚀行为

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In this study, a variety of magnetron sputtered binary and ternary thin film (approximately 1.5 μm thick) coatings using Cr, Al, and C as base elements were deposited onto Ni-201 alloy and investigated before and after exposure to simulated Type Ⅱ Hot Corrosion environment. Prototypical Na_2SO_4 was applied to the samples before exposure for 250 hours in an air/SO_2 gas mixture at 700 °C. It was determined that all coatings reduced the samples specific mass gains (corrosion rates) when compared to uncoated ones. Binary Al - C and Cr - C coatings were completely dissolved after exposure testing and NiO was the only compound detected on the surfaces; whereas continuous layers of Al_2O_3 and Cr_2O_3 were detected in Cr - Al and Cr - Al - C coated samples, indicating good protection against Type Ⅱ Hot Corrosion.
机译:在这项研究中,将多种以Cr,Al和C为基础元素的磁控溅射二元和三元薄膜(约1.5μm厚)涂层沉积在Ni-201合金上,并在暴露于模拟的Ⅱ型热腐蚀之前和之后进行了研究。环境。将原型Na_2SO_4应用于样品,然后在700°C的空气/ SO_2气体混合物中暴露250小时。可以确定,与未涂层相比,所有涂层均降低了样品的比重(腐蚀速率)。暴露测试后,二元Al-C和Cr-C涂层完全溶解,NiO是在表面上唯一检测到的化合物。而在Cr-Al和Cr-Al-C涂层样品中检测到连续的Al_2O_3和Cr_2O_3层,表明对Ⅱ型热腐蚀具有良好的防护作用。

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