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The Changes in Physicochemical Properties of Lacquer Wax by Physical Adsorption and UV Light

机译:物理吸附和紫外光对漆蜡理化性质的影响

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In order to make the dark green pigments fade away and broaden the appliance of lacquer wax, both physical adsorption and ultraviolet (UV) irradiation were optimized and further compared in this paper. The optimal conditions of physical discoloration could be achieved in 80 °C when 20 mL petroleum ether blends with 1 g raw wax assisted by 5 % activated carbon/kieselguhr (1:1, m/m) as an adsorbent for 30 min, twice. A good bleaching effect of lacquer wax of UV radiation can be reached in 60 °C for 60 h. The CIEL~*a~*b~* system and Hunter whiteness formula were used to evaluate the discoloration effect. The value of peroxide, iodine, acid, and relative contents were imported to present the physical-chemical characterizations alteration. The chemical constituents variation of lacquer wax during the discoloration process was detected by GC-MS analyzer. A sharp increase of whiteness (by 54 %) occurred after these two processes and insignificant decrease in physical-chemical qualities indicated an effective and specificity method.
机译:为了使深绿色颜料褪色并扩大漆蜡的使用范围,本文对物理吸附和紫外线照射均进行了优化,并进行了进一步比较。当20 mL石油醚与1 g生蜡在5%活性炭/硅藻土(1:1,m / m)辅助下作为吸附剂共混30分钟时,可以在80°C下实现最佳的物理变色条件。在60°C下60 h可以达到UV辐射漆蜡的良好漂白效果。用CIEL〜* a〜* b〜*体系和Hunter白度公式评价变色效果。输入过氧化物,碘,酸和其相对含量的值来表示其物理化学特征的变化。用GC-MS分析仪检测变色过程中漆蜡的化学成分变化。在这两个过程之后,白度急剧增加(增加了54%),而物理化学性质的微不足道的降低则表明这是一种有效而专一的方法。

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