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Single particle characterization of black carbon aerosol in the Northeast Tibetan Plateau, China

机译:中国东北高原黑碳气溶胶的单颗粒特征

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An SP2and a CO instrument were deployed at Qinghai Lake in the NortheastTibetan Plateau from October 16 to 27, 2011 to characterize rBC mass size distribution and mixing state, and of the relationships of rBC loading to CO mass mixing ratio. The area was not pristine, with an average measured rBC mass concentration of 0.36 μg STP-m~(-3). rBC concentration peaked at night with low concentrations in the afternoon. This diurnal cycle was loosely anticorrelated with the mixed layer depth, consistent with trapping of local emissions at night, and increased ventilation during the day. Measurements in the late afternoon and early evening, when the mixed layer depths were the highest, were representative of the larger Tibetian Plateau region with an average rBC concentration of 0.23 μg STP-m~(-3). A lognormal primary mode with MMD of ~175-nm and a small secondary lognormal mode with MMD of 470-500 nm (volume-equivalent diameter assuming 2 g cm~(-3) void free density) were observed. Relative reduction in the secondary mode during a snow event supports recent work suggesting size dependent removal of BC by precipitation. rBC was strongly correlated with CO, with different correlation slopes depending on air mass and local wet deposition. The data, in addition to constraining rBC loadings and microphysical state in the sparsely sampled Tibetan plateau region, improves sampling of as yet poorly understood features of rBC aerosol in China and strengthens conclusions about size dependent removal of BC via precipitation.
机译:2011年10月16日至27日至27日至27日,在东北地区高原的青海湖部署了一个SP2和CO仪器,以表征RBC质量尺寸分布和混合状态,以及RBC负荷与CO质量混合比的关系。该区域不是原始的,平均测量的RBC质量浓度为0.36μgSTP-M〜(-3)。 RBC浓度在晚上达到夜晚,下午低浓度。该昼夜循环与混合层深度松散地吻合,与夜间局部排放的诱捕一致,并在白天增加通风。在下午晚些时候和傍晚的测量,当混合层深度最高时,较大的藏高平台区域的代表性是平均RBC浓度为0.23μgSTP-m〜(-3)。观察到具有MMD的Lognormal主模式和具有470-500nm的MMD的小型次级逻辑模式(假设2g cm〜(-3)空隙的空隙不密度)。雪事件期间的次要模式的相对减少支持最近的工作,提出了沉淀的尺寸依赖性去除BC。 RBC与CO强烈相关,具有不同的相关性斜率,这取决于空气质量和局部湿沉积。除了在稀疏采样的藏高原地区限制RBC载荷和微神经状态之外,还提高了中国RBC气溶胶的特征,并加强了关于依赖于沉淀的大小依赖性去除的结论的研究。

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