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Leaching of Chromium Metal from High Carbon Fly Ash Stabilized Highway Base Layers

机译:从高碳粉煤灰稳定的公路基层中浸出铬金属

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Fly ash produced by power plants in the United States occasionally contains significant amountsof unburned carbon due to the use of low nitrogen-oxide and sulphur-oxide burners in recentyears. This ash cannot be reused in concrete production due to its reactivity with air entrainmentadmixtures and is largely placed in landfills. Roadways have high potential for large volume useof high carbon fly ash (HCFA). HCFA can be activated with lime kiln dust (a disposed residue oflime production plants) and used as the base layer for newly paved roads. However, in suchapplications, the leaching of heavy metals from fly ash-stabilized base layers can causesignificant environmental concerns. A series of column leach tests (CLTs) were conducted toinvestigate the leaching potential of chromium (Cr) from the fly ash-stabilized soils. The resultsindicate that an increase in LKD amount, pH, and fly ash content have significant effects onleaching behavior of heavy metals from soil-fly ash mixtures. The leaching of Cr in CLTsexhibited a first flush pattern, and the concentrations quickly decreased to below EPA maximumconcentration limits (MCLs) for drinking waters. In addition, a groundwater contaminationmodeling computer program (WiscLEACH) was used to estimate the Cr concentrations atdifferent depths and distances from the center alignment of the center of the HCFA stabilizedbase layer.
机译:美国发电厂产生的粉煤灰偶尔含有大量 最近由于使用低氮氧化物和硫氧化物燃烧器而导致的未燃烧碳排放量 年。由于这种灰分与空气夹带具有反应性,因此无法在混凝土生产中重复使用 外加剂,主要放置在垃圾填埋场中。巷道具有大批量使用的潜力 高碳粉煤灰(HCFA)。 HCFA可以用石灰窑粉尘(已处置的残留物)活化。 石灰生产厂),并用作新铺设的道路的基础层。但是,在这样的 在应用中,从粉煤灰稳定的基层中浸出重金属可能会导致 重大的环境问题。进行了一系列的柱浸试验(CLT) 研究了从粉煤灰稳定的土壤中铬(Cr)的浸出潜力。结果 表明LKD量,pH和粉煤灰含量的增加对 土壤-粉煤灰混合物中重金属的浸出行为。 CLT中Cr的浸出 表现出第一个冲洗模式,并且浓度迅速降低到EPA最大值以下 饮用水的浓度限值(MCL)。另外,地下水污染 建模计算机程序(WiscLEACH)用于估算Cr的浓度 距离稳定的HCFA中心的中心线不同的深度和距离 基层。

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