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Novel system of electro-catalysts for oxygen reduction based on organic metal complexes in acidic media for PEMFCs

机译:基于PEMFC酸性介质中有机金属络合物的新型氧还原电催化剂体系

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Aiming at new cost-effective, high performance catalyst for low temperature polymer electrolyte membrane fuel cells (PEMFCs), partial or complete replacement of Pt metal has been under great effort by many research groups, due to the slow kinetics of the oxygen reduction reaction (ORR) in acid media (1). There have so far been proposed several kinds of Pt-free catalysts which have shown remarkable catalytic activity toward oxygen reduction, such as oxides (2) carbonized catalase (3) Pd-, Ir- Ru-based alloy catalysts (3-6), pyrolyzed macrocyclic compounds (7,8) and non-precious catalysts (9).
机译:针对新型的低成本,高性能的低温聚合物电解质膜燃料电池(PEMFC)催化剂,由于氧还原反应的动力学缓慢,许多研究小组一直在努力部分或完全替代Pt金属( ORR)在酸性介质(1)中。迄今为止,已经提出了几种对氧气还原表现出显着催化活性的无Pt催化剂,例如氧化物(2)碳化过氧化氢酶(3)Pd-,Ir-Ru基合金催化剂(3-6),热解大环化合物(7,8)和非贵金属催化剂(9)。

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