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Stable aqueous dispersions of ZnO nanoparticles for ink-jet printed gas sensors

机译:用于喷墨印刷气体传感器的ZnO纳米颗粒的稳定水分散体

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For the preparation of printable devices based on ZnO nanoparticles (ZnO NP), stable colloidal dispersions of these materials are highly desirable. ZnO NP have been synthesized by chemical vapor synthesis. The particles have a spherical shape with a narrow size distribution. Stable aqueous dispersions of the ZnO NP have been successfully prepared after the addition of a polymeric stabilizer. The prepared dispersions are stable for at least 2 months without observable sedimentation. These stable dispersions are used to prepare ZnO NP films on different substrates by ink-jet printing. The viscosity and the surface tension of the dispersion as well as the printing parameters have been optimized for forming layers with high quality. Dense and low porosity layers of ZnO NP with a thickness between 100-250 nm have been prepared on different substrates. First measurements on ink-jet printed ZnO films are done on self fabricated inter digital capacitors (IDCs) at room temperature. The ZnO films show resistivity at room temperature of 7.76 k¿.cm. For sensing measurements in hydrogen atmosphere, the sheet resistance decreases rapidly until it reaching metallic behavior. This behavior is reversible.
机译:为了制备基于ZnO纳米颗粒(ZnO NP)的可印刷装置,这些材料的稳定的胶态分散体是非常需要的。 ZnO NP是通过化学气相合成法合成的。颗粒具有狭窄的尺寸分布的球形。加入聚合物稳定剂后,已成功制备了稳定的ZnO NP水性分散液。制备的分散体稳定至少2个月,没有可观察到的沉淀。这些稳定的分散体用于通过喷墨印刷在不同的基材上制备ZnO NP膜。分散液的粘度和表面张力以及印刷参数已经过优化,可形成高质量的层。已经在不同的基底上制备了厚度在100-250 nm之间的ZnO NP致密低孔隙率层。喷墨印刷的ZnO薄膜的首次测量是在室温下在自制的叉指电容器(IDC)上完成的。 ZnO膜在室温下显示为7.76kΩ.cm的电阻率。为了在氢气氛中感应测量,薄层电阻迅速减小,直到达到金属性能为止。此行为是可逆的。

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