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Pseudo-second-order Model for Sorption of Nickel (Ⅱ) onto Peat

机译:泥炭中镍(Ⅱ)的吸附的伪二阶模型

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Peat contains many functional groups, such as alcohols, aldehydes, acids, and phenolic hydroxides which can be involved in chemical bonding with metallic ions. The use of peat for removal of nickel from aqueous solution has been investigated at various a-queous pH values by means of liquid scintillation counting. The present research shows that the ability of binding Ni on peat increases with increment of aqueous pH values and reaches the adsorption equilibrium rapidly. A reasonable kinetic model, pseudo - second - order model, has been developed and fitted for sorption of nickel (Ⅱ) onto peat. The pseudo - second - order model provides a high degree of correlation with the experimental data for the sorption of nickel on to peat.
机译:泥炭包含许多官能团,例如醇,醛,酸和酚式氢氧化物,它们可能与金属离子发生化学键合。借助于液体闪烁计数,已经研究了在不同的a水溶液pH值下使用泥炭从水溶液中去除镍的方法。目前的研究表明,镍在泥炭上的结合能力随水溶液pH值的增加而增加,并迅速达到吸附平衡。建立了一个合理的动力学模型,即伪二级模型,并将其拟合为将镍(Ⅱ)吸附到泥炭上。伪二级模型与镍在泥炭上的吸附实验数据高度相关。

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