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Microchemical reactors for heterogeneously catalzed reactions

机译:适用于非均相催化反应的微化学反应器

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The application of precision engineering techniques to chemical reaction engineering has been idntified as having numerous potnetial advantages for both the chemical process development and manufacture of chemicals. Most developed are the microfabricated components which perform the standard unit operatins, i.e. micropumps, microvalves, micro heat exchanger and separation units. In comparison, the ongoing development of chemical microreactors acquires more effort for the availability of effective and reliable reactors, especially for heterogeneously catalyzed reactions. It is the purpose of this paper to briefly describe the intellectual and experimental ways of down scaling from industrially used multitube fixed bed reactor to microreactors including some illustrated applications. From the preceding information, we conclude that the extremely rapid heat and mass transport what is available through the engineered microstructures yielding reactors with high selectivities and even reaction rates. The development of microreactors for heterogeneously catalyzed reactions at present are focused on providing sufficient amounts of catalytic active material on the walls of the mirostructures. This was identified as a crcial prerequisite for an extended variety of possible applications and assembling microchemical systems including the required unit operations as well as sensors, analyzers and electronic units for process managing and controlling. When the desired chemical microreactors and corresponding systems are available, they provide opportunities for point-of-use production of chemicals, for the time being in small, high purity amounts and also of inflammable or hazardous intermediates with storage and transportation restrictions.
机译:精密工程技术在化学反应工程中的应用已被确定为在化学工艺开发和化学制造方面均具有众多潜在的优势。开发最先进的是执行标准单元操作的微型组件,即微型泵,微型阀,微型热交换器和分离单元。相比之下,化学微反应器的不断发展为有效和可靠的反应器的可用性付出了更多的努力,特别是对于非均相催化反应。本文的目的是简要描述从工业上使用的多管固定床反应器到微型反应器的缩小规模的智力和实验方法,包括一些图解的应用。从前面的信息中,我们得出结论,通过工程化的微结构可以实现极快的热量和质量传递,从而产生具有高选择性和均匀反应速率的反应器。目前,用于异相催化反应的微反应器的开发集中于在微结构的壁上提供足够量的催化活性材料。这被认为是扩展各种可能应用和组装微化学系统(包括所需的单元操作以及用于过程管理和控制的传感器,分析仪和电子单元)的重要先决条件。当所需的化学微反应器和相应的系统可用时,它们为使用点生产的化学品提供了机会,目前它们的数量少,纯度高,并且还具有易燃或危险的中间体,具有存储和运输限制。

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