首页> 外国专利> Process for the catalu00ectica heterogeneous reaction on a mixture of gas and lu00ecquido reagent in a reagent carrying a metal monolith reactor catalu00ectico of catalu00ectico under reaction conditions of the basisLu00ecquida for a time sufficient to generate carbonu00e3ceos and deactivating sub products and process for the catalu00ectica heterogeneous reaction on a mixture of hydrogen and dinitrotoluene in a reactor Catalu00ectico of monolith with nu00ecquel and palladium as metals catalu00ecticos under reaction conditions of phase for a time sufficient to generate lu00ecquida carbonaceous and deactivating sub products.

Process for the catalu00ectica heterogeneous reaction on a mixture of gas and lu00ecquido reagent in a reagent carrying a metal monolith reactor catalu00ectico of catalu00ectico under reaction conditions of the basisLu00ecquida for a time sufficient to generate carbonu00e3ceos and deactivating sub products and process for the catalu00ectica heterogeneous reaction on a mixture of hydrogen and dinitrotoluene in a reactor Catalu00ectico of monolith with nu00ecquel and palladium as metals catalu00ecticos under reaction conditions of phase for a time sufficient to generate lu00ecquida carbonaceous and deactivating sub products.

机译:在载有金属整体反应器的反应器中,在基于碱的反应条件下,在气体和液相混合物的混合物上进行催化异质反应的方法,反应时间应足以产生碳反应器中的氢和二硝基甲苯混合物上的氢催化剂和二硝基甲苯的混合物的钝化和失活副产物和方法在整相反应条件下,在正相和钯作为金属的条件下,整体催化剂的阳离子碳质和钝化副产品。

摘要

Process for the reaction catalu00ectica heterogeneous from a mixture of a gas and lu00ecquido reagent in a reagent carrying a metal monolith reactor catalu00ectico of catalu00ectico under reaction conditions of FasAnd for a time sufficient to generate lu00ecquida carbonaceous and deactivating sub products and process for the catalu00ectica heterogeneous reaction on a mixture of hydrogen and dinitrotoluene in a reactor.Lu00ectico of monolith with nu00ecquel and palladium as metals catalu00ecticos under reaction conditions of phase for a time sufficient to generate lu00ecquida carbonaceous and deactivating sub products ".The invention is a process for regenerating catalytic monolith reactors employed in the liquid phase hydrogenation reactions.Particularly those types of reactions involving nitroaromu00e1ticos compounds.The metal in the catalytic monolith catalytic reactor are deactivated by carbonaceous and sub products of deactivation and must be regenerated to extend the service life of the catalyst and reduce CCosts.The regeneration process involves two stage: initially through a gas mixture of oxidizau00e7u00e3o through catalytic monolith reactor at an elevated temperature and for a time sufficient pTo remove carbonaceous and deactivating sub products, and then passing a gas through the catalytic reduction reactor monolith previously exposed to gas under conditions to reduce the metal oxidizau00e7u00e3oA catalytic state reduced.
机译:在Fas的反应条件下,在载有金属整体反应器的催化剂中,从气体和液相混合物的混合物中异构化催化阳离子的方法,反应时间应足以产生碳酸和使氢和二硝基甲苯在反应器中的混合物上发生催化失活副产物和方法。整相中具有正癸酸和钯作为金属的正催化钯在相反应条件下反应足够长的时间本发明是用于液相加氢反应的催化整体式反应器的再生方法。特别是涉及硝基芳烃化合物的那些类型的反应。使催化整体式催化反应器中的金属失活通过碳质和副产物的失活而必须再生以延长再生过程涉及两个阶段:首先通过在高温下通过催化整体反应器将氧化的气体混合物氧化,并持续足够的时间以除去碳质和使副产物失活,然后使气体通过先前在一定条件下暴露于气体的催化还原反应器整体,以还原金属氧化态,使催化态还原。

著录项

  • 公开/公告号BR0204607A

    专利类型

  • 公开/公告日2003-09-16

    原文格式PDF

  • 申请/专利权人 AIR PRODUCTOS AND CHEMICALS INC.;

    申请/专利号BR20020204607

  • 发明设计人 KEITH ALLEN WELP;

    申请日2002-11-04

  • 分类号B01J37/16;B01J10/00;

  • 国家 BR

  • 入库时间 2022-08-22 00:03:40

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