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Influence of tin oxide microstructure on the sensitivity to reductor gases

机译:氧化锡微观结构对还原气体敏感性的影响

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The gas reponse of tin oxide sensors strongly depends on the preparation process and especially on depositioon parameters. For this reason, sensor elements have been prepared by depositing nanocrystalline tiun oxide at room temperature and at 250 deg C on polcrystalline alumina substrates by a reactive sputtering technique. It is seen that the response to gases is depednent on the tin oxide deposition temperature due to the structure change undergone by the oxide. The best resonse to low concentrations of carbon monoside and propanal is given by tin oxide sensors deposited at 250 deg C. Microstructural examination of these devices has been carried out using transmission electron mcroscopy. THe main difference observed in the tin oxide microstructure is the porosity. Sensors prepared at 250 deg C has a more compact microstructure.
机译:氧化锡传感器的气体响应在很大程度上取决于制备过程,尤其取决于沉积参数。因此,已经通过反应溅射技术通过在室温和250℃下在纳米晶氧化铝基板上沉积纳米晶氧化钛来制备传感器元件。可以看出,由于氧化物的结构变化,对气体的响应在氧化锡沉积温度上是不重要的。在250摄氏度下沉积的氧化锡传感器可对低浓度的碳单侧和丙醛产生最佳共振。这些设备的微结构检查已使用透射电子显微镜进行。在氧化锡微结构中观察到的主要区别是孔隙率。在250摄氏度下制备的传感器具有更紧凑的微观结构。

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