Etch characteristics of Ti in Cl2/N2 and TiN in Cl2/N2/BCl3 plasmas by response surface methodology

摘要

The etch characteristics of titanium (Ti) film in Cl$- 2$//N$-2$/ plasmas and titanium nitride (TiN) film in Cl$- 2$//N$-2$//BCl$-3$/ plasmas are examined by design of experiment using central composite-face centered type design and modeled by response surface methodology (RSM). The Ti and TiN etch experiments are carried out in a Lam Research Rainbow 4600 single wafer parallel plate metal etcher. For the Ti etch process, the effects of variation of the process parameters such as Cl$-2$/, N$-2$/ gas flow, RF power and reaction pressure on output responses, etch rate and etch uniformity, are investigated. For TiN etch process, BCl$-3$/ gas flow is added as a factor in addition to the factors listed above. A statistical analysis software package, JMP, is used to design experiment and analyze the results. The factors are normalized with respect to center point for the design and analysis of the experiment in order to compare the relative significance of the model terms. Using the etch rate and uniformity data obtained from the experiment, a quadratic model is developed for etch rate and uniformity for each rate and uniformity data obtained from the experiment, a quadratic model is developed for etch rate and uniformity for each of the films. From the coefficients of the models thus developed, it is easy to determine the relative influence of the first and second order effects of factors, and two factor interactions on the etch rate and uniformity response. Contour plots, which are helpful in determining the optimum process window, are generated for both etch rate and uniformity factors. Addition of nitrogen is found to decrease the etch rate due to dilution effect. The reaction pressure decreases the etch rate probably due to loss of energies of radicals, ions and electrons. Increasing of all the factors except nitrogen flow lead to better etch uniformity. Increase in nitrogen flow is causing poor uniformity probably due to dilution of etchant species leading to across-the-wafer nonuniformity.