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Broadband dielectric spectroscopy on ferroelectric liquid crystalline polymers

机译:铁电液晶聚合物上的宽带介电光谱

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The collective and molecular dynamics of ferroelectric liquid crystalline side group polysiloxanes has been investigated for use of broadband dielectric spectroscopy (10$+$MIN@2$/ Hz - 10$+9$/ Hz). In the lower frequency range ($LS 10$+6$/ Hz) two collective relaxations, Goldstone- and soft-mode, could be observed. They are assigned to the fluctuations of the phase and the amplitude of the helical superstructure, respectively. In the high frequency regime (10$+6$/ Hz - 10$+9$/ Hz) one dielectric relaxation, the $beta@- relaxation, is found. It is assigned to the hindered rotation (libration) of the mesogene around its long molecular axis. It shows an Arrhenius-like temperature dependence with no deviations at the phase transition S$-A$//S$+*$/$-C$/. A dilution of the mesogenes causes a decrease of the collectivity but remains the local dynamics uninfluenced.
机译:已经研究了铁电液晶侧组聚硅氧烷的集体和分子动力学用于使用宽带介电谱(10 $ + $ MIN @ 2 $ / HZ - 10 $ + 9 $ / Hz)。在较低的频率范围内($ 10 $ + 6 $ / Hz)可以观察到两个集体放松,Goldstone和软模式。它们分别分配给螺旋上层结构的相位波动和螺旋上层结构的幅度。在高频制度(10 $ + 6 $ / Hz - 10 $ + 9 $ / Hz)中,一个介电放松,在$ BETA @ - 放松身上被发现。它被分配到围绕其长分子轴线的中间体的阻碍旋转(Libration)。它显示了像阶段过渡时没有偏差的Arrhenius的温度依赖性,而是在阶段-A $ // S $ + * $ / $ - C $ /。稀释的脱水剂导致集体减少,但仍然是局部动态不受影响。

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