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Broadband dielectric spectroscopy on ferroelectric liquid crystalline polymers

机译:铁电液晶聚合物的宽带介电谱

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Abstract: The collective and molecular dynamics of ferroelectric liquid crystalline side group polysiloxanes has been investigated for use of broadband dielectric spectroscopy (10$+$MIN@2$/ Hz - 10$+9$/ Hz). In the lower frequency range ($LS 10$+6$/ Hz) two collective relaxations, Goldstone- and soft-mode, could be observed. They are assigned to the fluctuations of the phase and the amplitude of the helical superstructure, respectively. In the high frequency regime (10$+6$/ Hz - 10$+9$/ Hz) one dielectric relaxation, the $beta@- relaxation, is found. It is assigned to the hindered rotation (libration) of the mesogene around its long molecular axis. It shows an Arrhenius-like temperature dependence with no deviations at the phase transition S$-A$//S$+*$/$-C$/. A dilution of the mesogenes causes a decrease of the collectivity but remains the local dynamics uninfluenced.!13
机译:摘要:研究了铁电液晶侧基聚硅氧烷在宽带介电谱(10 $ + $ MIN @ 2 $ / Hz-10 $ + 9 $ / Hz)中的集体和分子动力学。在较低的频率范围($ LS 10 $ + 6 $ / Hz)中,可以观察到两个集体松弛,即戈德斯通和软模式。它们分别被分配给螺旋上部结构的相位波动和振幅。在高频状态下(10 $ + 6 $ / Hz-10 $ + 9 $ / Hz),发现一种介电弛豫,即β-弛豫。归因于介基因绕其长分子轴的旋转(释放)。它显示出类似于Arrhenius的温度依赖性,在相变S $ -A $ // S $ + * $ / $-C $ /时没有偏差。介晶的稀释会导致整体性降低,但局部动力学不会受到影响!13

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