Anion-deficient corundum and TLD-500 detectors on their basis were studied for a possible correlation between the thermoluminescence (TL) yield in the high-temperature TL peak at 830 K and the transformation of intrinsic defects and contents of impurities. Only 40-60% of TLD-500 detectors were found to have 830 K TL peak. The efficiency of thermally stimulated direct conversion of F and F~+ centers in the 800-930 K region depends on the presence of TL peak at 830 K. Obtained data point to the quenching role of the Ti impurity in the formation of the 830 K TL peak. Also, these data provide indirect evidence of association of the 830 K TL peak with Cr~(3+) ions.
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机译:研究了阴离子缺乏循环和TLD-500探测器的基础上,用于在830K处的高温T1峰值中的热致发光(TL)产量与杂质的内在缺陷和含量的转化之间的可能相关性。发现只有40-60%的TLD-500探测器有830 k TL峰。 800-930k区域的热刺激直接转化的效率在800-930k区的情况下取决于830k的T1峰的存在。获得的数据指向Ti杂质在830 k的形成中的猝灭作用TL峰值。此外,这些数据提供了与Cr〜(3+)离子的830k T1峰的关联的间接证据。
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