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Characterizing the mechanism and rate of calcium phosphate precipitation in aerobic granular sludge

机译:表征好氧颗粒污泥中磷酸钙沉淀的机理和速率

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Aerobic granular sludge (AGS) is a promising technology that has demonstrated the ability to recover phosphorus through the precipitation of calcium phosphate minerals within granules~(1-3). However, more work is needed to better understand how to control and enhance mineral precipitation within the polymeric matrix of the granule as well as how the pre-existing mineral phases within the granule influence recovery. We performed calcium phosphate precipitation experiments using AGS in order to quantify the impact of calcium pre-enrichment and mineral presence on the extent and rate of phosphate removal. Results have indicated that calcium pre-enrichment and mineral accumulation increases the transition from amorphous calcium phosphate to more crystalline forms and increases the rate and magnitude of phosphorus removal. This work identifies conditions under which AGS enhances mineral phosphate precipitation and suggests that calcium treated granular sludge can be used to recover phosphorus as a stable calcium phosphate mineral
机译:好氧颗粒污泥(AGS)是一项很有前途的技术,它已显示出通过沉淀颗粒中的磷酸钙矿物质〜(1-3)来回收磷的能力。但是,需要做更多的工作来更好地理解如何控制和增强颗粒聚合物基质中的矿物质沉淀,以及颗粒中预先存在的矿物相如何影响回收率。我们使用AGS进行了磷酸钙沉淀实验,以量化钙预富集和矿物质的存在对磷酸盐去除的程度和速率的影响。结果表明,钙的预富集和矿物质积累增加了从无定形磷酸钙到更多结晶形式的过渡,并增加了除磷的速率和幅度。这项工作确定了AGS增强磷酸盐矿物质沉淀的条件,并表明经钙处理的颗粒污泥可作为稳定的磷酸钙矿物质回收磷。

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