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Thermal decomposition of some N-nitrozo-N-alkyl(aryl)hydroxylaminates

机译:某些N-硝基-N-烷基(芳基)羟基层压板的热分解

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摘要

Energetic characteristics of a family of new potassium and ammonium salts of N-nitrozo-N-alkyl(aryl)hydroxylamine were obtained via differential scanning calorimetry and quantum chemical techniques. The enthalpies of formation, combustion and detonation were calculated using mixed experimental and theoretical approaches. The dependencies between energetic proties and structural features of studied compounds are disscused.
机译:通过差示扫描量热法和量子化学技术获得了N-亚硝基-N-烷基(芳基)羟胺的新型钾盐和铵盐的能量特征。使用混合的实验和理论方法计算了生成,燃烧和爆轰的焓。讨论了能量性质与所研究化合物的结构特征之间的依赖性。

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