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APPLICATION OF ETCHING PASTE ON METALLIZATION OF INTERDIGITATED BACK-CONTACT NTYPE SILICON SOLAR CELLS

机译:黏贴剂在互反型N型硅太阳能电池金属化中的应用

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Metallization of interdigitated back-contact n-type c-Si solar cells has been fabricated by the application ofscreen-printing processes with etching paste for contact hole opening. The contact holes are formed by using etchingpaste to remove SiNx passivation layers on diffused silicon surface. Different contact open ratios of metallization are thenapplied to the back side of solar cells by either extending the size of each contact opening or the number of contact holes.Details of cell processing and related cell parameters are clearly shown and discussed in this paper. By increasing thecontact open ratio from 1.1% to 4.3%, Jsc of solar cells shows a great enhancement with ΔJsc~+7.7% while F.F. isslightly improved and Voc has not varied much (Δefficiency~+13.5%). Interdigitated back-contact solar cells with anappropriate contact open ratio can increase the probability of carrier collection to electrodes in the lateral direction andthus have higher Jsc as compared with those of low contact open ratios, e.g., 1.1% in our case. Besides, we also find thatoptimization of SiNx etching processes with etching paste is needed to prevent the over-etching of diffused siliconunderneath and lateral etching of SiNx thin films, especially for cells with large contact open opening and/or with a lowpitch distance between contact holes.
机译:指叉背接触n型c-Si太阳能电池的金属化已通过应用 丝网印刷工艺,采用蚀刻膏打开接触孔。接触孔通过蚀刻形成 粘贴以去除扩散的硅表面上的SiNx钝化层。然后得出不同的金属化接触开口率 通过扩展每个接触孔的尺寸或接触孔的数量,将其应用于太阳能电池的背面。 本文将清楚地显示和讨论单元格处理和相关单元格参数的详细信息。通过增加 接触开口率从1.1%到4.3%,太阳能电池的Jsc显着提高,ΔJsc〜+ 7.7%,而F.F.是 略有改善,VOC变化不大(Δefficiency〜+ 13.5%)。交叉指型背接触式太阳能电池 适当的接触开口率可以增加在横向方向上将载流子收集到电极的可能性,并且 因此,与低触点打开率(例如在我们的情况下为1.1%)相比,具有更高的Jsc。此外,我们还发现 需要使用蚀刻膏对SiNx蚀刻工艺进行优化,以防止扩散硅的过度蚀刻 在SiNx薄膜的下方和侧面蚀刻,特别是对于接触开口大和/或接触距离低的电池 接触孔之间的间距。

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