Development of a novel pvT measuring technique

摘要

The pressure-temperature-specific volume relation of polymers is important not only for physical chemistry, but they are very significant input data for injection molding simulation software. Today's methods for measuring pvT data are slow, measurements can take days to be carried out, and in many cases the accuracy of the measurement is unsatisfactory. In our work, a new measuring method has been developed which makes the determination of the pvT relation faster compared to conventional processes within injection molding processing conditions. For the measurements a special injection mould was developed, in which the pvT relation of the material can be determined from the shrinkage in the mold. The data measured by the new method using polypropylene at a mold temperature of 23°C were compared to the data given in the database of the simulation software.