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Challenges in the production of hydrogen from glycerol-a biodiesel byproduct via steam reforming process

机译:生物柴油副产品甘油蒸汽重整制氢面临的挑战

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The depleting fossil fuels with their ever increasing prices have paved ways for alternative fuels. Biodiesel is one of those alternative fuels which have picked up keen interest of the people due to its similar properties to diesel. However due to biodiesel being costlier than diesel in the present scenario, it has not been preferred to diesel. However if the cost of biodiesel is reduced then its effective usage can be made, either by blending with conventional diesel or by utilizing its byproduct (glycerol) effectively. One way is to use glycerol to produce hydrogen. Hydrogen, being another source of renewable energy, is also seen as a clean fuel for transportation purpose. Hydrogen can be prepared through glycerol via various routes namely steam reforming, auto-thermal reforming, partial oxidation, etc. The paper here focuses on the steam reforming process. This process is used widely used in the industries and it would not require much change in the system if the feedstock is changed to glycerol from naphtha or natural gas. However like every process this process also has some limitations which hinder the effective production of hydrogen. The paper throws light on these challenges, along with few possible solutions which can be used in order to avoid or eliminate these challenges and help in efficient production of hydrogen.
机译:日益枯竭的化石燃料及其不断上涨的价格为替代燃料铺平了道路。生物柴油是一种与柴油性质相似的替代燃料,受到人们的广泛关注。然而,由于在目前的情况下,生物柴油的成本高于柴油,因此它并不是首选柴油。然而,如果生物柴油的成本降低,那么可以通过与传统柴油混合或有效利用其副产品(甘油)来有效利用生物柴油。一种方法是使用甘油生产氢气。氢是另一种可再生能源,也被视为用于运输目的的清洁燃料。甘油可以通过多种途径制备氢气,即蒸汽重整、自动热重整、部分氧化等。本文重点介绍了蒸汽重整过程。该工艺在工业中得到广泛应用,如果将原料从石脑油或天然气改为甘油,则无需对系统进行太多改变。然而,与所有工艺一样,该工艺也有一些限制,阻碍了氢气的有效生产。本文阐明了这些挑战,以及一些可能的解决方案,以避免或消除这些挑战,并帮助高效生产氢气。

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