Thermal decomposition of Mannich's bases on the base of 1-methyl-3-carbamido-1,2,4-triazole

摘要

The thermal decomposition kinetics of Mannich's bases on the base of 1-methyl-3-carbamido-1,2,4-triazole in the solution is studied by manometric method under the static conditions with the use of chromato-mass-spectrometry. The mechanism of decomposition is established. The activation parameters are determined for the limiting stage and the correlation equations are found, which connect the rate constant with the ionization constant of the outgoing nitro compound anion.