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Preparation and Application of Starch-Acrylamide-Diallyl Dimethyl Ammonium Chloride Graft Copolymer

机译:淀粉-丙烯酰胺-二烯丙基二甲基氯化铵接枝共聚物的制备及应用

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The starch-acrylamide-diallyl dimethyl ammonium chloride graft copolymer (St-AM-DADMAC copolymer) was prepared firstly. Then the synthesized St-AM-DADMAC copolymer was analyzed by FTIR and SEM. Finally the synthesized St-AM-DADMAC copolymers were applied in making packaging paper, the first pass retention and the mechanical properties of the made packaging paper were determined. The FTIR of St-AM-DADMAC copolymer indicated that AM and DADMAC can be grafted in the chain of starch. The SEM of starch and St-AM-DADMAC copolymer indicated that the surface of starch had been changed obviously by grafting copolymerization. The first pass retention increased with the increase of degree of cationic of St-AM-DADMAC copolymer. When the dosage of St-AM-DADMAC copolymer was about 1% and the degree of cationic of St-AM-DADMAC copolymer was about 25.96%, the mechanical properties of the packaging paper were improved best.
机译:首先制备淀粉-丙烯酰胺-二烯丙基二甲基氯化铵接枝共聚物(St-AM-DADMAC共聚物)。然后通过FTIR和SEM对合成的St-AM-DADMAC共聚物进行了分析。最后将合成的St-AM-DADMAC共聚物用于包装纸,测定了包装纸的初次通过率和机械性能。 St-AM-DADMAC共聚物的FTIR表明AM和DADMAC可以接枝在淀粉链中。淀粉和St-AM-DADMAC共聚物的SEM图像表明,接枝共聚可明显改变淀粉的表面。初次保留率随St-AM-DADMAC共聚物阳离子度的增加而增加。当St-AM-DADMAC共聚物的用量约为1%,且St-AM-DADMAC共聚物的阳离子度约为25.96%时,包装纸的机械性能得到最好的改善。

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