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MODIFIED BY WOOD FILLERS RECYCLEDPOLYETHYLENE FOR EUROPALLETS APPLICATION

机译:由木材填料改性的聚乙烯改性,用于欧洲托盘

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One of the possibilities of reinforcement of polyolefines is adding diverse fillers likeglass or carbon fibers (but they are rather expensive) and natural fillers like wood, plants and others.It’s especially important for wasted of low density polyethylene which has low modulus. For the testsit was used waste polyethylene (LDPE) from industrial and consumption films and as reinforcement itwas used wood fibers LIGNOCEL CB 120 supplied by J. Rettenmaier & S?hne GmbH+Co. This filleris made of coniferous soft trees, it has fibrous structure and it particle size is 70 – 150 μm. For the testsit was prepared three kinds of composite materials with 10% (PE1), 20% (PE2) and 30% (PE3) ofwood fibers. Besides for comparison it was tested original polyethylene (PE0) and next was testedspecimens cut out from produced europallets (with 15% of wood fibers). It was tested mechanicalproperties all prepared composite materials like tensile strength, stress and bending e-modulus, impactstrength, Brinell hardness and processing properties like melt flow, Vicat point and additionallydensity (balance of liquid method), water absorption and photos on optical and SEM microscope.Tests of mechanical properties during tension and bending show that properties connected withincreasing of straight and stiffness like e-modulus, tensile strength, hardness grow along with contentof wood fibers. However properties like strain at break or impact strength low with increase of amountof fillers. The Vicat point of tested composite materials was on the level about 98 – 100 0C and itdoesn’t change with increase of amount of fillers. Results of melt flow presents fall of processingproperties along with increase content of wood fibers. Using image analyzes it was shown distributionof wooden fibers for all tested composite materials. After comparison of all tests’ results we proposedone composite with 15% of wood fibers and reclaimed LDPE that to process pre-production batch ofeuropallet produced by Becker GmbH (extraction with pressing). Besides it distribution of stresses anddeflections of europallets was analyzed having various amount of wood fibers (by means of FEM -finite elements method) that to estimate their strength (HMH hypothesis) and reduction cost ofmaterial processing. Geometric and numeric models of analyzed pallets and bitch files prepared bymeans of Femap 7.1, calculations and postprocesing by Ansys 5.7. The low-filler reclaimedpolyethylene can be use on such products like wood decks, boxes, flower pots, automotive parts andothers building and building parts. On the base of done tests and numerical calculation it seems thatfilling of reclaimed LDPE by wood fibers has to be on the level 15 – 20% for optimal processing andproperties.
机译:增强聚烯烃的可能性之一是添加各种填料,例如玻璃纤维或碳纤维(但价格昂贵)和天然填料,例如木材,植物等。这对于浪费低模量的低密度聚乙烯尤为重要。在测试中,使用了工业和消费类薄膜中的废聚乙烯(LDPE),并使用了J. Rettenmaier&S?hne GmbH + Co提供的木质纤维LIGNOCEL CB 120作为增强材料。这种填充物由针叶软树制成,具有纤维状结构,粒径为70 – 150μm。为了进行测试,准备了三种复合材料,其中木纤维含量分别为10%(PE1),20%(PE2)和30%(PE3)。除了进行比较外,还测试了原始聚乙烯(PE0),然后测试了从生产的欧洲托盘(含15%的木纤维)上切下的标本。在光学和SEM显微镜上测试了所有制备的复合材料的机械性能,如拉伸强度,应力和弯曲电子模量,冲击强度,布氏硬度以及加工性能,如熔体流动性,维卡点和附加密度(液体平衡法),吸水率和照片在拉伸和弯曲过程中的机械性能测试表明,随着直线度和刚度的增加(例如电子模量,拉伸强度,硬度)的增加,性能随木纤维含量的增加而增加。但是,随着填料量的增加,诸如断裂应变或冲击强度之类的性能降低。经过测试的复合材料的维卡点在大约98 – 100 0C的水平,并且不会随填料量的增加而变化。熔体流动的结果表明,随着木纤维含量的增加,加工性能下降。使用图像分析显示了所有测试复合材料的木纤维分布。在比较所有测试结果之后,我们提出了一种复合材料,该复合材料包含15%的木纤维,并回收了LDPE,用于处理贝克尔有限公司生产的批量生产的欧泊石(压榨法提取)。除此之外,还分析了欧洲托盘的应力和挠度分布,该托盘具有各种数量的木纤维(通过FEM-有限元法),以估计其强度(HMH假设)并降低材料加工成本。由Femap 7.1编写的分析的货盘和母狗文件的几何和数字模型,由Ansys 5.7进行计算和后处理。低填充再生聚乙烯可用于诸如木甲板,盒子,花盆,汽车零件以及其他建筑和建筑零件之类的产品。根据已完成的测试和数值计算,似乎为达到最佳加工和性能,木质纤维对再生LDPE的填充量必须在15-20%的水平上。

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