SYNTHETIC METAL-TRANSITION METAL d,π-CONJUGATED COMPLEX SYSTEMS

摘要

Synthetic metal catalytic system is achieved in the polyaniline-or polypyrrole-catalyzed dehydrogenation reaction under oxygen. The dimensionally aligned π-conjugated systems are formed by the introduction of π-conjugated molecules to porphyrin scaffold. The higher catalytic activity is attained by the formation of synthetic metal-transition metal complexes. The π-conjugated polymers also serve as a redox-active ligand in the Wacker oxidation. The complexation is controlled to afford the structurally regulated complexes.