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Systematic analyses of practical problems related to defects and metallic impurities in silicon

机译:系统分析与硅中的缺陷和金属杂质有关的实际问题

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Systematic approaches are introduced for (i) oxygen precipitation behavior, which is important for internal gettering, and (ii) segregation induced gettering behaviors of p/p~+ epitaxial wafers and Poly-Si Back Seal (PHS) wafers. (i) Oxygen precipitation behavior during a whole sequence of a thermal process is predicted by a practical computer simulation technique involving a novel empirical function. The predicted oxygen precipitation behavior agrees with the corresponding experimental results reasonably well. (ii) For a systematic description of Fe segregation gettering, explicit expressions of the Fe segregation coefficients are obtained as functions of temperature and time. Using the determined expressions of the segregation coefficients and introducing diffusion dynamics, one can predict [Fe] behavior as a function of process time during a whole sequence of a thermal process. For both behaviors of (i) oxygen precipitation and (ii) segregationinduced gettering, experimentally observed characteristics of a high-temperature process and a low-temperature process are well understoody by aids of those simulations. (iii) For a high-sensitivity detection of an important heavy metal impurity Cu, we present a novel bulk impurity collection technique using a room-temperature Cu drift phenomenon accelerated by Corona charge showering on a Si wafer surface.
机译:针对(i)对内部吸杂很重要的氧沉淀行为和(ii)p / p〜+外延晶片和多晶硅反密封(PHS)晶片的偏析引起的吸杂行为,引入了系统的方法。 (i)通过涉及新型经验函数的实用计算机模拟技术来预测整个热处理过程中的氧气析出行为。预测的氧沉淀行为与相应的实验结果相当吻合。 (ii)为了系统地描述Fe偏析吸杂剂,获得了Fe偏析系数的明确表达式,作为温度和时间的函数。使用确定的偏析系数表达式并引入扩散动力学,可以预测[Fe]行为在整个热处理过程中随处理时间的变化。对于(i)氧沉淀和(ii)偏析引起的吸杂的两种行为,借助于这些模拟,可以很好地理解高温过程和低温过程的实验观察特性。 (iii)为了高灵敏度地检测重要的重金属杂质Cu,我们提出了一种新颖的块状杂质收集技术,该技术使用了通过在硅晶片表面上进行电晕电荷喷淋加速的室温Cu漂移现象。

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