EFFECT OF LIPID-PACKAGING ON THE CHARGE TRANSFER CHARACTERISTICS OF ONE-DIMENSIONAL, MIXED-VALENCE PLATINUM COMPLEXES

摘要

Lipid-packaged platinum complexes of [Pt(en)_2][PtX_2(en)_2] (X = Cl, Br, I) are newly synthesized and their morphology and charge transfer (CT) absorption characteristics are compared in organic media. They show remarkably red-shifted CT absorption characteristics, which are ascribed to the significantly promoted exciton delocalization along the chains.