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A RE-THINK OF THE MERCURY REMOVAL PROBLEM FOR LNG PLANTS

机译:对液化天然气工厂汞去除问题的重新思考

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Following the mercury induced catastrophic failure of a heat exchanger at Skikda in 1957, the LNG industry had to move quickly to install mercury removal units (MRUs) prior to liquefaction. At that time, the choice of absorbent was limited and MRUs had to be installed at the final stage of purification immediately prior to the cold box. This was not the best arrangement. By not treating the raw gas, mercury was left in co-produced NGLs and might also be released to the atmosphere during processing. Commissioning of new beds lengthened start up and the choice of location added to compression costs.rnThe arrival of new high activity mercury absorbents has allowed the re-thinking of the purification process. The MRU can now be located at the front of the plant to treat the raw gas thus avoiding mercury in NGLs or in emissions. The high activity allows smaller beds to be used and the use of radial flow reactors allows significant savings in compression costs over the traditional axial flow design. The new absorbents can be recycled through an audited disposal route.rnThis paper draws on data from actual operating MRUs to suggest how the design of LNG plants could be improved.
机译:继1957年汞在斯基克达(Skikda)引起的热交换器的灾难性故障之后,液化天然气行业不得不迅速采取行动,在液化之前安装除汞装置(MRU)。那时,吸收剂的选择受到限制,并且必须在冷却箱即将提纯的最后阶段安装MRU。这不是最好的安排。通过不处理原始气体,汞会残留在联产的NGL中,并且在加工过程中也可能释放到大气中。新床的调试延长了启动时间,位置的选择增加了压缩成本。rn新型高活性汞吸收剂的到来使人们重新思考了净化过程。现在,MRU可以位于工厂的前部,以处理原料气,从而避免了NGL或排放中的汞。高活性允许使用更小的床,并且与传统的轴向流设计相比,径向流反应器的使用可以显着节省压缩成本。新的吸收剂可以通过经审核的处置途径进行再循环。rn本文借鉴了实际运行的MRU的数据,提出了如何改进LNG工厂的设计的建议。

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