HIGH PERFORMANCE LONG-LIFETIME CHARGE-SEPARATION PHOTODETECTORS

摘要

High-performance long-lifetime charge-separation photodetectors are provided. A new device design is described based on novel band structure engineering of semiconductor materials for photodetectors, such as photosensors, solar cells, and thermophotovoltaic devices. In an exemplary aspect, photodetectors described herein include a charge-separated photo absorber region. This comprises a semiconductor with a band structure that has an indirect fundamental bandgap, with a direct bandgap (┌-┌ transition) only slightly above the indirect fundamental bandgap (L- or X-┌ transitions) (e.g., approximately equal to or larger than an energy of a product of the Boltzmann constant (kB), and temperature (T), with kBT=26 millielectron-volts (meV) at room temperature). This design not only improves photogenerated-carrier lifetime (similar to indirect bandgap semiconductors), but also maintains a strong absorption coefficient (similar to direct bandgap semiconductors).