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METHOD FOR PREPARING RARE EARTH-MODIFIED POLYETHERSULFONE ULTRAFILTRATION MEMBRANE

机译:制备稀土改性聚醚砜超滤膜的方法

摘要

A method for preparing a rare earth-modified polyethersulfone ultrafiltration membrane, comprising the steps of: dissolving lanthanum nitrate in deionized water to obtain a solution A, dissolving ammonium paratungstate and potassium carbonate in deionized water to obtain a solution B, and dissolving citric acid in ionized water to obtain a solution C; adding half of solution C to solution A and the other half to solution B, and separately stirring the mixed solutions; slowly adding solution A to solution B, and simultaneously adding ethylene glycol, heating the mixed solution to 65-70°C and stirring the same for 2-4 h to obtain a sol; transferring the obtained sol to a constant temperature blast drying oven and heating the sol for 25-27 h, and then transferring same to a vacuum drying oven to obtain a gel; stirring and dissolving dried PES, a porogen PEG400, and the gel prepared above in DMAC, leaving the solution to stand for deaeration, scraping the membrane on a glass plate with a scraper, and then putting the membrane into ultrafiltered water to form a natural membrane to obtain the product. The polyethersulfone flat membrane with the rare earth added has a notably increased pure water flux and improved mechanical properties, and has a significant antibacterial effect.
机译:一种制备稀土化改性聚醚砜超滤膜的方法,包括以下步骤:将硝酸镧溶解在去离子水中,得到溶液A,溶解铵副烷酮和碳酸钾在去离子水中,得到溶液B,并溶解柠檬酸离子水以获得溶液c;将一半的溶液C加入溶液A和另一半至溶液B,​​并分别搅拌混合溶液;缓慢加入溶液A至溶液B,​​同时加入乙二醇,加热混合溶液至65-70℃并搅拌2-4小时以获得溶胶;将获得的溶胶转移到恒温喷砂干燥炉中并加热溶胶25-27小时,然后将其转移到真空干燥烘箱中以获得凝胶;搅拌和溶解干燥的PES,致孔剂PEG400和在DMAC中制备的凝胶,使溶液脱离,脱液,用刮刀将膜刮在玻璃板上,然后将膜放入超滤水中以形成天然膜获得产品。加入稀土的聚醚砜平膜具有显着增加的纯净水通量和改善的机械性能,具有显着的抗菌作用。

著录项

  • 公开/公告号WO2021237381A1

    专利类型

  • 公开/公告日2021-12-02

    原文格式PDF

  • 申请/专利权人 HAIMEN MAOFA ART DESIGN CO. LTD.;

    申请/专利号WO2020CN91949

  • 发明设计人 XIE CHAO;

    申请日2020-05-23

  • 分类号B01D69/02;B01D69/06;B01D67;

  • 国家 CN

  • 入库时间 2022-08-24 22:37:29

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