首页> 外国专利> A method for producing an ethylene-based polymerization catalyst component, a method for producing an ethylene-based polymerization catalyst, and a method for producing an ethylene-based polymer.

A method for producing an ethylene-based polymerization catalyst component, a method for producing an ethylene-based polymerization catalyst, and a method for producing an ethylene-based polymer.

机译:一种制备基于乙烯的聚合催化剂组分的方法,一种制备乙烯基聚合催化剂的方法,以及制备乙烯基聚合物的方法。

摘要

PROBLEM TO BE SOLVED: To provide a method for producing a catalyst component having good particle properties, which can stably produce an ethylene-based polymer having an ultra-high molecular weight component. A method for producing an ethylene-based polymerization catalyst component in which steps (1), (2), and (3) are sequentially performed. Step (1): The slurry of component A and component B is spray-dried and granulated to be granulated to obtain granulated particles. Step (2): The granulated particles are impregnated with a chromium compound in the presence of a solvent having a relative permittivity (ε0) of 50 or less at 25 ° C. to obtain a chromium compound-bearing component. Step (3): By removing the solvent in step (2), a fluid chromium compound-supporting component is obtained. Component A: Inorganic oxide having characteristics 1 and 2. (Characteristic 1) The ratio Py / Px of the peak intensity Py maximum in the range Y to the peak intensity Px maximum in the range X in the infrared absorption spectrum is less than 10. (Characteristic 2): Contains 90% by weight or more of SiO2. Component B: Fine particle inorganic oxide. [Selection diagram] Fig. 1
机译:要解决的问题:提供一种制备具有良好颗粒性质的催化剂组分的方法,其可以稳定地产生具有超高分子量组分的基于乙烯的聚合物。一种制备基于乙烯的聚合催化剂组分,其中依次进行步骤(1),(2)和(3)。步骤(1):将组分A和组分B的浆液喷雾干燥并造粒以造粒以获得颗粒状颗粒。步骤(2):在25℃的相对介电常数(ε0)的溶剂存在下,将粒状颗粒浸渍有铬化合物,以获得25℃的相对介电常数(ε0)以获得铬化合物成分。步骤(3):通过在步骤(2)中除去溶剂,获得流体铬化合物载体组分。组分A:具有特征1和2的无机氧化物(特征2):含有90%重量或更多的SiO2。组分B:细颗粒无机氧化物。 [选择图]图1

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