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WATER-BASED ANTI-CORROSION COATING COMPOSITION

机译:水性防腐涂料组合物

摘要

The invention pertains to an aqueous coating composition comprising: —an aqueous latex of a copolymer consisting essentially of recurring units derived (i) from vinylidene chloride (VDC), (ii) from vinyl chloride (VC), (iii) from one or more than one alkyl (meth)acrylate having from 1 to 12 carbon atoms in the alkyl group [monomer (MA)] and (iv) from one or more than one aliphatic alpha-beta unsaturated carboxylic acids [monomer (AA)], the proportion of recurring units derived from monomer (AA) being of at least 1.0 wt %, with respect to the total weight of the copolymer [copolymer (A)], wherein: (A) the said copolymer (A) is stable against dehydrochlorination, in a manner such that the total chloride content of the solid residue of the aqueous latex, after thermal treatment at about 120° C. for 2 hours, is of less than 1000 ppm, with respect to the total weight of the copolymer (A); (B) the said copolymer (A) does not to undergo any significant crystallization upon heating, in a manner such that the ratio of (j) its crystallinity index (CI) after a thermal treatment involving heating at 60° C. for 48 hours to (jj) its crystallinity index before such thermal treatment (Clafter thermal treatment/CIbefore thermal treament) is less than 1.15; and —at least one anti-corrosion pigment comprising an aluminium salt of a (poly)phosphoric acid modified with an alkaline earth metal oxide [pigment (P)]; —at least one non-ionic surfactant [surfactant (NS)]; and —at least one inorganic filler [filler (I)] different from pigment (P), in an amount such that the overall pigment volume concentration (PVC), comprehensive of pigment (P) and filler (I), is comprised from 20 to 40% vol., when determined with respect to the dried coating composition.
机译:本发明涉及水性涂料组合物,其包含:---基本上由来自氯乙烯(II)的重复组成的共聚物的含水胶乳,其来自氯乙烯(VC),(III)的重复组成(I),来自一种或多种在烷基[单体(MA)]和(IV)中具有1至12个碳原子的一种(甲基)丙烯酸酯,来自一种或多于一个脂族α-β不饱和羧酸[单体(aa)],比例相对于共聚物的总重量[共聚物(a)],其中:(a)所述共聚物(a)稳定,其衍生自单体(aa)的重量为至少1.0wt%,其中:(a)稳定的脱氯化氯化物稳定,一种方式,使得水性胶乳的固体残余物的总氯化物含量,在约120℃的热处理2小时后,相对于共聚物(A)的总重量小于1000ppm; (b)所述共聚物(a)在加热时不经历任何显着的结晶,以使(J)其结晶度指数(CI)的比例在涉及在60℃下加热48小时的热处理之后(JJ)其结晶性指数在此类热处理(刷新热处理/ Cibefore热序)小于1.15之前; - 至少一种抗腐蚀颜料,其包含用碱土金属氧化物改性的(聚)磷酸的铝盐[颜料(P)]; - 至少一种非离子表面活性剂[表面活性剂(NS)]; - 至少一种无机填料[填料(I)]不同于颜料(p),其中总颜料体积浓度(pvc),颜料综合(p)和填料(i)组成为20当相对于干燥的涂料组合物确定时,达到40%Vol。

著录项

  • 公开/公告号EP3430098B1

    专利类型

  • 公开/公告日2021-09-29

    原文格式PDF

  • 申请/专利权人 SOLVAY SA;

    申请/专利号EP20170710005

  • 申请日2017-03-14

  • 分类号C09D127/08;C08K3/32;C09D5/08;

  • 国家 EP

  • 入库时间 2022-08-24 21:21:11

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