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water-based anti-corrosion coating composition

机译:水性防腐涂料组合物

摘要

The invention pertains to an aqueous coating composition comprising: - an aqueous latex of a copolymer consisting essentially of recurrent units derived from (i) vinylidene chloride (vdc), (ii) vinyl chloride (vc), (iii) one or more than one alkyl (meth) acrylate having from 1 to 12 carbon atoms in the alkyl group [monomer (ma)] and (iv) one or more than one unsaturated alpha-beta aliphatic carboxylic acid [monomer ( aa)], the proportion of recurrent monomer-derived units (aa) being at least 1.0% by weight, with respect to the total weight of the copolymer [copolymer (a)], wherein: (a) said copolymer ( (a) is stable against dehydrochlorination, in such a way that the total chloride content of the solid residue of the aqueous latex after heat treatment at about 120 ° C for 2 hours is less than 1000 ppm with respect to weight total copolymer (a); (b) said copolymer (a) undergoes no significant crystallization during heating, in such a manner that the ratio of (j) its crystallinity index (ci) after heat treatment involving heating at 60 ° C for 48 hours. hours for (jj) its crystallinity index prior to such heat treatment (ci after heat treatment / prior to heat treatment) is less than 1.15; and at least one anti-corrosion pigment comprising an aluminum salt of a (poly) phosphoric acid modified with an alkaline earth metal oxide.
机译:本发明涉及一种水性涂料组合物,其包含:-共聚物的乳胶,其基本上由衍生自(i)偏二氯乙烯(vdc),(ii)氯乙烯(vc),(iii)一种或多种的重复单元组成的共聚物在烷基中具有1至12个碳原子的(甲基)丙烯酸烷基酯[单体(ma)]和(iv)一种或多种一种不饱和α-β脂肪族羧酸[单体(aa)],循环单体的比例相对于共聚物[共聚物(a)]的总重量,衍生单元(aa)为至少1.0重量%,其中:(a)所述共聚物(a)以这种方式对脱氯化氢是稳定的。相对于共聚物(a)的总重量,在约120℃下热处理2小时后的水性胶乳的固体残余物的总氯含量小于1000ppm;(b)所述共聚物(a)没有显着变化加热过程中的结晶,以(j)其结晶度指数之比(ci)包括在60℃下加热48小时的热处理后。 (jj)在这种热处理之前(热处理之后/热处理之前的ci)的结晶度小时数小于1.15;至少一种抗腐蚀颜料,其包含用碱土金属氧化物改性的(聚)磷酸的铝盐。

著录项

  • 公开/公告号BR112018068257A2

    专利类型

  • 公开/公告日2019-01-15

    原文格式PDF

  • 申请/专利权人 SOLVAY SA;

    申请/专利号BR20181168257

  • 申请日2017-03-14

  • 分类号C08K3/32;C09D5/08;C09D127/08;

  • 国家 BR

  • 入库时间 2022-08-21 12:03:29

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