It is described a Zinc-Iron rechargeable flow battery, comprising a first half-cell containing a first electrolyte which Zn2+ ions are dissolved, connected in a closed-loop configuration to a first external tank containing the first electrolyte; a second half-cell containing a second electrolyte in which Fe2+ and Fe3+ ions are dissolved, connected in a closed-loop configuration to a second external tank containing the second electrolyte; and a separator between the two half-cells.
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