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EMULSION EXPLOSIVE COMPOSITION AND METHOD FOR PRODUCTION THEREOF

机译:乳液炸药组合物及其制备方法

摘要

FIELD: explosives.;SUBSTANCE: group of inventions relates to industrial explosives used in the mining industry for initiating borehole and blasthole charges, breaking dimensional stone, producing cumulative and pressure charges, and to a method of producing an emulsion composition. An emulsion explosive composition based on a matrix emulsion is comprised of water, an oxidizing phase comprising ammonium nitrate mixed with sodium or calcium nitrate, a hydrocarbon phase comprising ceresin or microcrystalline wax, and an emulsifier. A water solution of sodium nitrite or glass or polymer microspheres are used as a sensitizing agent. Polyisobutylene succinic anhydride sorbitan is used as an emulsifier. The composition is characterized by the following ratio of components, % wt.: sodium or calcium nitrate or ammonium perchlorate 5 to 25.0; water 5.0 to 20.0; ceresin, microcrystalline wax or mixtures thereof with saturated hydrocarbons with a dropping point of more than 60°С 4.0 to 7.0; polyisobutylene succinic anhydride sorbitan 0.5 to 2.0; a water solution of sodium nitrite at a concentration of 5 to 25% 0.5 to 2.0 or glass or polymer microspheres 0.4 to 5.0; the rest ammonium nitrate up to 100%. The emulsion explosive composition based on a matrix emulsion is produced from a dispersion of a water solution of oxidizing salts in a medium based on molten ceresin or microcrystalline wax with a dropping point of at least 60°C and a solid emulsifier with a sensitizing additive introduced thereto. The process is executed at a temperature of 85 to 95°С. The resulting emulsion is filled into a mold to be formed into cartridges, cumulative charges or detonator blocks, followed by cooling.;EFFECT: provided are stability of form during storage, transportation and application and high explosive characteristics. ;7 cl, 1 tbl
机译:领域:炸药。物质:发明组涉及采矿业中使用的工业炸药,用于启动钻孔和吹孔电荷,破碎尺寸石,产生累积和压力,以及生产乳液组合物的方法。基于基质乳液的乳液炸药组合物由水,包含硝酸铵与硝酸钠或硝酸钙的氧化铵,包含Ceresin或微晶蜡的烃相和乳化剂。亚硝酸钠或玻璃或聚合物微球的水溶液用作敏化剂。聚异丁烯琥珀酸酐脱水山梨糖醇用作乳化剂。该组合物的特征在于以下成分比例,%wt .:钠或硝酸钙或硝酸钙或高氯酸铵5至25.0;水5.0至20.0; Ceresin,微晶蜡或其混合物与饱和烃,滴落点大于60°С.0至7.0;聚异丁烯琥珀酸酐山梨糖醇0.5至2.0;亚硝酸钠水溶液,浓度为5-25%0.5-2.0或玻璃或聚合物微球0.4至5.0;其余硝酸铵高达100%。基于基质乳液的乳液炸药组合物由氧化盐水溶液的水溶液在基于熔融的Ceresin或微晶蜡中的水溶液的分散体中制备,其中滴注点和具有敏化添加剂的固体乳化剂引入此外。该过程在85至95°С的温度下执行。将所得乳液填充到盒中以形成盒,累积电荷或雷管块,然后冷却。;效果:在储存,运输和应用过程中提供的稳定性和高爆炸性特征。 ; 7 cl,1 tbl

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