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Preparation of high density anode with reduced graphene oxide-silicon metal particle compound and fabrication of electrodes for secondary battery and process for preparing the same

机译:用氧化石墨烯 - 硅金属颗粒化合物的高密度阳极的制备以及二次电池的电极制造及其制备方法

摘要

The present invention relates to a method for manufacturing a high-density negative electrode material including a graphene oxide reduced product-silicon metal particle complex, and an electrode for a secondary battery including the negative electrode material prepared thereby, and a graphene oxide reduced product through a cation-pi interaction Graphene oxide reduced product manufacturing step of producing a; The composite using any one of a first process of coating a polymer on silicon metal particles and then complexing it with the graphene-reduced material and a second process of coating the polymer on the graphene oxide-reduced material and then complexing it with the silicon metal particles. A composite dispersion solution preparation step of preparing a dispersion solution; A composite powder manufacturing step of spray-drying the composite dispersion solution to prepare a composite powder having a core-shell structure; A slurry preparation step of preparing a negative electrode material slurry by mixing natural graphite and artificial graphite with the composite powder; And a negative electrode material manufacturing step of applying the slurry to a current collector. The electrode for a secondary battery including the negative electrode material manufactured thereby can improve high capacity and stable cycle performance.
机译:本发明涉及一种制造包括石墨烯氧化物还原的产品 - 硅金属颗粒复合物的高密度负极材料的方法,以及包括由此制备的负电极材料的二次电池的电极,并通过氧化石墨烯氧化物阳离子 - PI相互作用石墨烯氧化物还原产物制造步骤的生产步骤;使用第一工艺中的任何一种在硅金属颗粒上涂覆聚合物中的任何一种,然后用石墨烯 - 减少的材料络合,并在石墨烯氧化物还原材料上涂覆聚合物,然后用硅金属络合粒子。一种制备分散溶液的复合分散溶液制备步骤;喷雾干燥复合分散液的复合粉末制造步骤,制备具有芯壳结构的复合粉末;通过将天然石墨和人造石墨与复合粉末混合制备负极材料浆料的浆料制备步骤;和将浆料施加到集电器的负极材料制造步骤。用于包括所制造的负极材料的二次电池的电极可以提高高容量和稳定的循环性能。

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