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DISPERSANT FOR POLYMER POLYOL AND PREPARATION METHOD OF POLYMER POLYOL

机译:聚合物多元醇的分散剂及聚合物多元醇的制备方法

摘要

The invention discloses a dispersant for polymer polyol and a preparation method of polymer polyol, wherein the dispersant is a copolymer macromolecule prepared by the propylene oxide or ethylene oxide with an average molecular weight of 6000 to 20000, with containing at least one benzene ring group and one polymerizable carbon-carbon double or triple bond polymer. The preparation method of the dispersant is: synthesizing a basic polyether polyol, adding a cyclic dicarboxylic anhydride into the polyether polyol, then the polyether polyol is reacted with an epoxy compound with the polymerizable double bond, and capping with an epoxy compound to obtain the dispersant; preparing the polymer polyol by the basic polyol, an unsaturated vinyl monomer styrene and acrylonitrile, a polymerization initiator, the dispersant and an optional chain transfer agent; the basic polyether is a polyether polyol with a functionality of 3 to 8. The invention can obtain a stable, colorless and transparent dispersant, and the POP prepared therefrom has not only a relatively low viscosity, but also fine particles, high whiteness and good water solubility.
机译:本发明公开了一种用于聚合物多元醇的分散剂及聚合物多元醇的制备方法,其中,分散剂是由环氧丙烷或环氧乙烷的共聚物大分子,其平均分子量为6000至20000,其中含有至少一种苯环组和一种可聚合的碳 - 碳双或三键聚合物。分散剂的制备方法是:合成碱性聚醚多元醇,将环状二羧酸酐加入聚醚多元醇中,然后将聚醚多元醇与可聚合的双键反应,并用环氧化合物覆盖以获得分散剂;用碱性多元醇制备聚合物多元醇,不饱和乙烯基单体苯乙烯和丙烯腈,聚合引发剂,分散剂和可选的链转移剂;碱性聚醚是具有3至8的官能度的聚醚多元醇。本发明可以获得稳定,无色透明的分散剂,并且由此制备的流体不仅具有相对低的粘度,而且还具有细颗粒,高白度和良好的水溶解度。

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