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A method for the production of peroxide, durable pastes with delayed, long permanent oxidation effect

机译:一种具有过长时间的持久氧化作用的过氧化物耐用糊剂的生产方法

摘要

1,163,309. Polyethylene oxide compositions. ELEKTROCHEMISCHE WERKE MœNCHEN A.G. 7 Dec., 1966 [15 Dec., 1965], No. 54773/66. Heading C3R. A peroxide-containing paste which may be used for curing unsaturated polyester or acrylic resins comprises; (a) a. solid organic peroxide, (b) water, and (c) a polyethylene oxide material which melts at a temperature below that at which the peroxide decomposes and which in admixture with (a) and (b) melts at below ambient temperature, such material being one or more polyethylene oxide compounds optionally admixed with up to 20% by weight of the entire composition of one or more organic compounds which are soluble therein and do not react with the components of the composition. Polyethylene glycols are preferred as the polyethylene oxide material. The organic peroxide may represent from 20-65% by weight of the composition and water from 2-30% by weight of the peroxide. Hydrophobic de-sensitizers for the peroxide, such as phthalic acid esters, and which are soluble in the polyethylene oxide, may be incorporated into the composition and the paste may also contain dispersing or emulsifying agents, e.g. alkyl phenyl polyglycol ethers.
机译:1,163,309。聚环氧乙烷组合物。 ELEKETROCHEMISCHE WERKE MHENNCHEN A.G.,1966年12月7日[1965年12月15日],编号54773/66。标题C3R。可用于固化不饱和聚酯或丙烯酸树脂的含过氧化物的糊包括: (a)固态有机过氧化物,(b)水和(c)聚环氧乙烷材料,其熔点低于过氧化物分解的温度,并且与(a)和(b)的混合物在低于环境温度的温度下熔融,一种或多种聚环氧乙烷化合物任选地与占整个组合物的至多20重量%的一种或多种有机化合物混合,所述一种或多种有机化合物可溶于其中并且不与组合物的组分反应。聚乙二醇优选作为聚环氧乙烷材料。有机过氧化物可占组合物重量的20-65%,水占过氧化物重量的2-30%。可以将对过氧化物的疏水性脱敏剂,例如邻苯二甲酸酯,可溶于聚环氧乙烷中,并入组合物中,并且糊剂还可以包含分散剂或乳化剂,例如聚对苯二甲酸乙二醇酯。烷基苯基聚乙二醇醚。

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