首页> 外国专利> Biocidal 1,2,4-triazol-3-yl dimethylcarbamates - prepd. by reacting 3-hydroxy-5-thio-1,2,4-triazoles with dimethylcarbamoyl chloride

Biocidal 1,2,4-triazol-3-yl dimethylcarbamates - prepd. by reacting 3-hydroxy-5-thio-1,2,4-triazoles with dimethylcarbamoyl chloride

机译:杀菌的1,2,4-三唑-3-基二甲基氨基甲酸酯-制备。使3-羟基-5-硫代-1,2,4-三唑与二甲基氨基甲酰氯反应

摘要

Compounds of formula (I) (where R1 is (cyclo)alkyl; R2 is alkylthio the alkyl chain of which may be interrupted by O or S, cycloalkylthio, haloalkylthio, alkenylthio, alkynylthio, alkyl-CO-CHR3-S-, alkyl-O-CO-CHR3-S-, H2N-CO-CHR3-S-, alkyl-NH-COCHR3-S-, (alkyl)2N-CO-CHR3-S- or NC-CHR3-S-; and R3 is H or alkyl) are prepd. by reacting dimethylcarbamoyl chloride with a cpd. of formula (III), the reaction being carried out in the presence of an acid binding agent or (III) being used in the form of its (alkyl)ammonium or monovalent metal salt. (I) have broad biocidal activity and are particularly useful as insecticides and acaricides. They are also active against phytopathogenic fungi, bacteria and phytopathogenic nematodes. (I) also have herbicidal activity (total or selective, depending on rate of application).
机译:式(I)的化合物(其中R 1为(环)烷基; R 2为烷硫基,其烷基链可被O或S中断),环烷硫基,卤代烷硫基,烯基硫基,炔基硫基,烷基-CO-CHR 3 -S-,烷基- O-CO-CHR3-S-,H2N-CO-CHR3-S-,烷基-NH-COCHR3-S-,(烷基)2N-CO-CHR3-S-或NC-CHR3-S-;且R3为H或烷基)。使二甲基氨基甲酰氯与cpd反应在式(III)的式(III)中,反应在酸结合剂的存在下进行,或(III)以其(烷基)铵或一价金属盐的形式使用。 (I)具有广泛的杀生物活性,尤其可用作杀虫剂和杀螨剂。它们还对植物病原真菌,细菌和植物病原线虫具有活性。 (I)也具有除草活性(全部或选择性,取决于施用量)。

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