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proceedings of the svelenamento hydrocyanic acid gas and gas nitrodi and its application to solid substances containing cyanide and nitrites

机译:velvementment氢氰酸气体和亚硝基二硝基甲烷的合成工艺及其在含有氰化物和亚硝酸盐的固体物质中的应用

摘要

The detoxification of gaseous HCl and nitrous gases is achieved by reacting these in the gas phase, pref. at 25-1400 degrees C and opt. in the presence of a catalyst, pref, a Pt gp. metal or an oxide of Fe, Ni, Cu, Cr and/or Bi and pref. in the absence of O2. Any excess nitrous gases present after reaction can be reduced to N2 in a reducing flame. NO, NO2 and N2O4 react with HCN, giving CO2 and N2, even at low temps., although the reaction is accelerated by the use of a higher temp. and/or a catalyst. The process is useful for the detoxification of solids contg. cyanides and nitrites, esp. hardening salts, which are treated with acid to liberate the toxic gases.
机译:气态HCl和亚硝酸气体的脱毒是通过使它们在气相中反应而实现的。选择在25-1400摄氏度之间。在催化剂(优选Pt gp)的存在下。金属或铁,镍,铜,铬和/或铋的氧化物以及优选。在没有氧气的情况下反应后存在的任何过量的亚硝酸气体可在还原火焰中还原为N2。 NO,NO2和N2O4与HCN反应,即使在低温下也能生成CO2和N2,尽管使用较高的温度会加速反应。和/或催化剂。该方法可用于固体的排毒。尤其是氰化物和亚硝酸盐。硬化盐,用酸处理可释放有毒气体。

著录项

  • 公开/公告号IT1041394B

    专利类型

  • 公开/公告日1980-01-10

    原文格式PDF

  • 申请/专利权人 FAIRTEC AG;

    申请/专利号IT19750068861

  • 发明设计人

    申请日1975-07-16

  • 分类号B01D;

  • 国家 IT

  • 入库时间 2022-08-22 18:17:35

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