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Process for improving the color yield and fastness properties of dyeings produced with anionic dyes on cellulose fibre material and cationic fibre- reactive compounds

机译:改善在纤维素纤维材料和阳离子纤维反应性化合物上用阴离子染料生产的染料的色产量和牢固性的方法

摘要

A process for improving the color yield and the wetfastness properties of dyeings produced on cellulose fibre material with anionic dyes, which process comprises treating the cellulose material before, during or after dyeing, with a cationic fibre-reactive compound of the formula ##STR1## wherein B represents a mono- or polynuclear heterocyclic radical,P PHal represents a reactive halogen atom, PP X represents halogen, lower alkoxy, lower alkylthio, phenoxy, phenylthio, ##STR2## or the group of the formula ##STR3## each of W.sub.1 and W.sub.2 independently represents the direct bond, ##STR4## Z represents hydrogen, lower alkyl or hydroxy-lower alkyl, each of Q.sub. 1 and Q.sub.2 independently represents an aliphatic or cycloaliphatic radical,P Peach ofPPR.sub.1, R.sub.2, V. sub.1, V.sub.2, Y. sub.1 and Y.sub.2 independently represents lower alkyl, or lower alkyl or benzyl each of which is substituted by halogen, hydroxy or cyano, or each of the pair of substituents R.sub.1 and R.sub.2 and Y.sub.1 and Y. sub.2 together with the nitrogen atom to which it is attached independently represents a 5- or 6-membered heterocyclic ring, or each ofP PR.sub.1, R.sub.2 and V.sub.1 and Y.sub.1, Y. sub.2 and V.sub.2 together with the nitrogen atom to which it is attached independently represents a pyridine ring, or, if W.sub.1 and W.sub.2 are ##STR5## each of Z and V. sub.1 and Z and V.sub.2 together with the group N--Q.sub. 1 --N or N--Q.sub.2 --N independently also represents a divalent heterocyclic radical,PPAn ⊖ represents the anion of an organic or inorganic acid, and n is 1 or 2, P Pwith the proviso that an optional aftertreatment of the cellulose material is carried out according to a padding process.
机译:一种用于改善用阴离子染料在纤维素纤维材料上生产的染料的颜色产率和湿牢度特性的方法,该方法包括在染色之前,之中或之后,用式## STR1#的阳离子纤维反应性化合物处理纤维素材料。 #其中B代表单核或多核杂环基,

Hal表示反应性卤素原子,

X表示卤素,低级烷氧基,低级烷硫基,苯氧基,苯硫基,## STR2 ##或W.sub.1和W.sub.2各自独立的式## STR3 ##的基团代表直接键,## STR4 ## Z代表氢,低级烷基或羟基-低级烷基,每个Q子1和Q 2独立地表示脂族或脂环族基团,每个P 1 P 2,V 1,V 2 .2,Y.sub.1和Y.sub.2分别代表各自被卤素,羟基或氰基取代的低级烷基或低级烷基或苄基,或成对的取代基R.sub.1和R子2和Y 1和Y 2与其独立连接的氮原子一起代表5或6元杂环,或每个P R R 1和R 2和V 1和Y 1,Y 2和V 2以及与其相连的氮原子一起独立地代表吡啶环,或者,如果W.sub.1和W.sub.2分别是Z和V.sub.1以及Z和V.sub.2的## STR5 ##以及> N--Q.sub。 1 -N <或> N-Q 2 -N <也独立地表示二价杂环基。代表有机或无机酸的阴离子,并且n为1或2,条件是根据填充工艺对纤维素材料进行任选的后处理。

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