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Canal clathrate complex solid electrolyte cell

机译:渠道包合物复合固体电解质电池

摘要

An electrolytic cell wherein one of the elements is comprised of a canal clathrate complex of benzophenone and a polyiodide salt of a cation from a group consisting of potassium (K.sup.+), sodium (Na.sup.+), cesium (Cs. sup.+), lithium (Li.sup.+), ammonium (NH.sub.4.sup.+), rubidium (Rb. sup.+) and tetraalkylammonium (R.sub.4 N.sup.+ where R is an alkyl group of less than five carbons). This complex functions through its tunnel- like dispositions of the cations, having certain unfilled sites and certain other sites occupied by the CHCl.sub.3 molecule, as a solid fast ion conductor. The same composition, again apparently because of the canal clathrate complex crystal structure, is adapted, by virtue of its electronic conductivity to function as an electrode in an electrolytic cell.
机译:一种电解池,其中的一种元素由二苯甲酮的笼形笼络合物和阳离子的聚碘化物盐组成,该钾盐由钾(K +),钠(Na +),铯(Cs sup +),锂(Li +),铵(NH 4 + +),rub(Rb +)和四烷基铵(N 4 N +) R是少于五个碳的烷基。这种复合物通过阳离子的隧道状排列而发挥功能,这些阳离子具有某些未填充的位点和CHCl 3分子占据的某些其他位点,作为固体快速离子导体。同样显然是由于管形笼形复合晶体结构的相同组成,由于其电子导电性而适合用作电解池中的电极。

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