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Liquid crystal mixtures comprising weakly polar non-cyano components and strongly polar cyano components

机译:包含弱极性非氰基组分和强极性氰基组分的液晶混合物

摘要

Liquid crystal mixtures having a net positive dielectric anisotropy comprise a weakly polar ( DELTA epsilon /=3) anisotropic non-cyano component (A) and a strongly polar (( DELTA epsilon /=5) anisotropic cyano component (B), the mixture of (A) and (B) containing from 50 to 95 mole % of component (B). Component (A) consists of not more than 5 compounds of the formula: (I) R1-A1-Z1[A2-Z2]m-A3-R2 and component (B) consists of not more than 5 compounds of the formula R3-A4-Z3-[A5-Z4]p-A6-CN (III in which formulae: R1, R2 and R3 are the same or are different and each is an n-alkyl, n-alkoxy, n- alkylamino, n-acyloxy or n-alkoxycarbonyl group containing not more than 12 carbon atoms in a chain (provided that component (A) consists of compounds in which one of R1 and R2 is a group containing not more than three atoms in a chain or component (B) consists of compounds in which R3 is a group containing not more than three atoms in a chain); A1, A2, A3 and A4 is each a ring of the formula: IMAGE m is 0, 1 or 2; p is 0 or 1; and Z1, Z2, Z3 and Z4 are the same or are different and each is a covalent bond or a methylenoxy, ethylene, or carboxyl group (provided that Z1 and Z2 and/or Z3 and Z4 are not both carboxyl groups and Z3 is not a carboxyl group when, p is zero and either A4 and A6 are both rings of formula (1a) or A4 is a ring of formula (1b).
机译:具有净正介电各向异性的液晶混合物包含弱极性(DELTA epsilon / = 5)各向异性的氰基组分(B), (A)和(B)的混合物含有50-95摩尔%的组分(B),组分(A)由不超过5种下式的化合物组成:(I)R 1 -A 1- Z 1 [A 2 -Z 2] mA 3 -R 2和组分(B)由不超过5种式R 3 -A 4 -Z的化合物组成<3>-[A 5 -Z 4] pA 6 -CN(III)其中,式:R 1,R 2和R 3相同或不同,各自是在链中包含不超过12个碳原子的正烷基,正烷氧基,正烷基氨基,正酰氧基或正烷氧基羰基(条件是组分(A)由其中R 1之一的化合物组成) R 2为链中含有不超过三个原子的基团或组分(B)由化合物组成,其中R 3为链中含有不超过三个原子的基团); <1>,A <2>,A <3>和A <4>分别为下式的环: m为0、1或2; p为0或1; Z 1,Z 2,Z 3和Z 4相同或不同,分别为共价键或亚甲基氧基,亚乙基或羧基(只要Z 1和Z当p为零且A 4和A 6均为环的环时,<2>和/或Z 3和Z 4既不是羧基,Z 3也不是羧基。式(1a)或A 4为式(1b)的环。

著录项

  • 公开/公告号GB2092169A

    专利类型

  • 公开/公告日1982-08-11

    原文格式PDF

  • 申请/专利权人 BROWN BOVERI BBC & CO LTD;

    申请/专利号GB19810037642

  • 发明设计人

    申请日1981-12-14

  • 分类号C09K3/34;

  • 国家 GB

  • 入库时间 2022-08-22 12:18:04

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