首页> 外国专利> SINGLE-PHASE, STABLE, SALTY POLYOL COMPOSITIONS WITH A HIGH ETHYLENE GLYCOL OR BUTANDIOL CONTENT AND THEIR USE FOR THE PRODUCTION OF POLYURETHANES

SINGLE-PHASE, STABLE, SALTY POLYOL COMPOSITIONS WITH A HIGH ETHYLENE GLYCOL OR BUTANDIOL CONTENT AND THEIR USE FOR THE PRODUCTION OF POLYURETHANES

机译:具有高乙二醇或丁二醇含量的单相,稳定,咸味多元醇组合物,及其在生产聚氨酯中的用途

摘要

A single-phase, storage-stable, emulsifier-free polyol mixture comprising 100 parts of a relatively high molecular weight polyoxyalkylene polyol of OH number from 20 to 120, which has at least 5% and less than 80% by weight, of terminal oxyethylene blocks; from 1 to 100 parts of a low molecular weight diol mixture which is a reaction product of ethylene glycol, butane diol-1,4, or a mixture of ethylene glycol and butane diol-1,4, with from 0.05 to 0.50 mols of alkyl oxiranes; from 0.1 to 5 parts of solubilizing additives comprising one or more salts, the cations of which are from Groups I, II and III of the Periodic Table, ammonium or mono- to tetra-alkyl ammonium ions, and the anions of which are produced by removing at least one proton from an acid having a Ks value of at least 10-7; and, optionally, other compounds having isocyanate-reactive hydrogen atoms and other auxiliaries and additives for polyurethane production. Also polyurethanes produced using these polyol mixtures.
机译:一种单相,储存稳定,无乳化剂的多元醇混合物,包含100份OH值为20至120的相对较高分子量的聚氧化烯多元醇,其中末端氧乙烯的含量至少为5%且小于80%块; 1至100份低分子量二醇混合物,该混合物为乙二醇,1.4丁烷二醇或14,000乙二醇和丁二醇1,4的混合物与0.05至0.50摩尔的烷基的反应产物环氧乙烷0.1-5份增溶添加剂,包含一种或多种盐,其阳离子来自周期表的I,II和III组,铵或单或四至四烷基铵离子,其阴离子由从具有至少10-7的Ks值的酸中去除至少一个质子;以及任选地,其他具有异氰酸酯反应性氢原子的化合物以及用于聚氨酯生产的其他助剂和添加剂。还使用这些多元醇混合物生产聚氨酯。

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