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NOVEL IMIDAZOLINE-ISOCYANURIC ACID ADDUCT, SYNTHESIS OF SAID ADDUCT, AND CURING OF POLYEPOXY RESIN CONTAINING SAID ADDUCT AS ESSENTIAL COMPONENT
NOVEL IMIDAZOLINE-ISOCYANURIC ACID ADDUCT, SYNTHESIS OF SAID ADDUCT, AND CURING OF POLYEPOXY RESIN CONTAINING SAID ADDUCT AS ESSENTIAL COMPONENT
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机译:新型咪唑啉-异氰尿酸加成,合成的合成加成和包含作为基本成分的合成的聚甲醛树脂的固化
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摘要
NEW MATERIAL:The imidazoline-isocyanuric acid adduct of formula I (R2 is alkyl or aryl; R4 is H or methyl). EXAMPLE:2-Undecylimidazoline-isocyanuric acid adduct. USE:A hardener for epoxy resin for the production of epoxy resin powder coating having excellent storage stability, insulation property, heat-resistance, low- temperature curability, yellowing resistance and self-extinguishing property, and a cure accelerator or co-hardener of an acid anhydride and dicyandiamide. PREPARATION:The compound of formula I can be produced easily in high yield by reacting isocyanuric acid with imidazoline of formula II in hot water at a molar ratio of about 1:1, and filtering the crystal precipitated by cooling.
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机译:新材料:式I的咪唑啉-异氰尿酸加合物(R 2为烷基或芳基; R 4为H或甲基)。实施例:2-十一烷基咪唑啉-异氰尿酸加合物。用途:用于环氧树脂粉末涂料生产的环氧树脂固化剂,具有优异的储存稳定性,绝缘性,耐热性,低温固化性,耐黄变性和自熄性,以及固化促进剂或共固化剂。酸酐和双氰胺。制备:通过使异氰尿酸与式II的咪唑啉在热水中以约1:1的摩尔比反应,并过滤冷却沉淀的晶体,可以容易地高收率地制备式I的化合物。
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