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Process for the preparation of compositions of poly propylene impact resistant having improved re-consistency bleaching

机译:制备具有改进的再稠化漂白性的聚丙烯抗冲击组合物的方法

摘要

Polypropylene compositions having a high impact resistance at low temperatures and an improved whitening resistance, comprising :… A) 60-90 parts by weight of polypropylene with an isotacticity index 90;… B) 10-40 parts by weight of an ethylene/butene-1 polymeric mixture containing 50-95% by weight of ethylene consisting of:… - 20-95% parts by weight of a crystalline fraction (I) with crystallinity of the polyethylene type, insoluble in xylene at room temperature;… - 5-80% parts by weight of an ethylene/butene-1 amorphous copolymeric fraction (II), soluble in xylene at 23 DEG C, containing 40-70% by weight of ethylene;… and in which the weight ratio between the total polymerized ethylene and the amorphous fraction (II) ranges from 0.6 to 8. …??Such compositions are obtained through polymerization processes comprising at least a step for homopolymerizing propylene to stereoregular polymer and a subsequent step for copolymerizing ethylene/butene-1 mixtures in the presence of Ziegler-Natta stereospecific catalysts, which include a titanium compound carried on a magnesium halide in the active form.
机译:具有低温下的高抗冲击性和改进的耐白化性的聚丙烯组合物,包括:A)60-90重量份等规立构指数> 90的聚丙烯;…B)10-40重量份乙烯/丁烯-1含有50-95%重量的乙烯的聚合物混合物,其中包括:...-20-95%重量份的结晶级分(I),具有聚乙烯类型的结晶度,在室温下不溶于二甲苯;…-5- 80重量份的乙烯/丁烯-1无定形共聚部分(II),在23℃下可溶于二甲苯,含有40-70重量%的乙烯;…,其中总的聚合乙烯与该无定形部分(II)的范围为0.6至8。…该组合物是通过聚合方法获得的,该方法包括至少一个将丙烯均聚为立构规整聚合物的步骤以及随后的在存在下使乙烯/丁烯-1混合物共聚的步骤。 Ziegler- Natta立体有择催化剂,其中包括以活性形式负载在卤化镁上的钛化合物。

著录项

  • 公开/公告号ES545638A0

    专利类型

  • 公开/公告日1986-10-01

    原文格式PDF

  • 申请/专利权人 HIMONT INCORPORATED;

    申请/专利号ES19850545638

  • 发明设计人

    申请日1985-07-29

  • 分类号C08L23/16;

  • 国家 ES

  • 入库时间 2022-08-22 07:37:46

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