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INSECTICIDE, ACARICIDE AND LAVRICIDE COMPOSITIONS CONTAINING NEOFANE ANALOGUES AS ACTIVE COMPONENTS AND PROCESS FOR PRODUCING THE ACTIVE COMPONENTS

机译:含有新氟烷类似物作为活性成分的杀虫剂,杀螨剂和杀虫剂组合物,以及制备该活性成分的方法

摘要

Compounds of the formula (I) and their stereoisomers IMAGE (I) wherein A, B, C' and D independently of one another denote CH or N, in which at least one of the symbols A, B, C' or D must correspond to a nitrogen atom, X denotes CH2 or oxygen, R1 denotes a radical bonded to a carbon atom from the series comprising H, trialkylsilyl, halogen, nitro, cyano, alkenyl, alkynyl, amino, cycloalkyl, phenyl, phenxy, alkoxy, alkenyloxy, alkynyloxy, hydroxycarbonyl, alkylthio, cycloalkyloxy, alkylcarbonyl, alkoxycarbonyl, alkenyloxycarbonyl, alkynyloxycarbonyl, halogenoalkyl, alkoxyalkyl, halogenoalkoxy, halogenoalkylthio, halogenoalkoxyalkyl, alkylthioalkyl, alkoxyalkoxy, halogenoalkoxyalkoxy, alkenyloxyalkoxy, halogenoalkenyloxy, alkoxyalkylthio, alkylthioalkoxy, alkylthioalkylthio, halogenoalkoxycarbonyl, halogenoalkenyloxycarbonyl or dialkylamino or two radicals R1 when they are positioned ortho to one another together denote a methylenedioxy, ethylenedioxy or alkylene radical, R2 and R3 independently of one another denote alkyl, alkenyl or phenyl, or R2 and R3 denote an alkylene chain which-together with the quaternary carbon atom-forms an unsubstituted or fluorinesubstituted ring having three to six ring members, R4 denotes -H, F, -CN, -CCl3, -C 3BOND CH, (C1-C4)alkyl, -C-NH2, S R5 denotes pyridyl, furyl or thienyl which can all be substituted, phthalimidyl, dialkylmaleimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl or substituted phenyl, or R4 and R5-together with the carbon atom bridging them-denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical and n denotes 0, 1 or 2, possess advantageous properties for combating pests, in particular insects and acarids. Furthermore, processes for the preparation of compounds of the formula I are described.
机译:式(I)的化合物及其立体异构体<图像>(I),其中A,B,C'和D彼此独立地表示CH或N,其中至少一个符号A,B,C'或D必须表示一个氮原子,X表示CH2或氧,R1表示一个键合至碳原子的基团,该基团包括H,三烷基甲硅烷基,卤素,硝基,氰基,烯基,炔基,氨基,环烷基,苯基,苯氧基,烷氧基,烯基氧基,炔基氧基,羟基羰基,烷硫基,环烷氧基,烷基羰基,烷氧基羰基,烯基氧基羰基,炔基氧基羰基,卤代烷基,烷氧基烷基,卤代烷氧基,卤代烷硫基,卤代烷氧基烷基,烷硫基烷基,烷氧基烷氧基,卤代烷氧基烷硫基,硫代烷氧基烷硫基,硫代烷氧基烷基硫代烷基,当两个基团R 1彼此邻位时,它们一起表示亚甲基二氧基,亚乙基二氧基或亚烷基基团,其中R 2和R 3彼此独立地表示烷基,烯基或苯基,或R 2和R 3表示与季碳原子一起形成具有三至六个环成员的未取代或氟取代的环的亚烷基链,R 4表示-H,F,-CN ,-CCl 3,-C 3 BOND CH,(C 1 -C 4)烷基,-C-NH 2,S R 5表示吡啶基,呋喃基或噻吩基,它们都可以被取代,邻苯二甲酰亚胺基,二烷基马来酰亚胺基,硫代邻苯二甲酰亚胺基,二氢邻苯二甲酰亚胺基,四氢邻苯二甲酰亚胺基或取代的苯基,或R 4。 R 5和与它们桥接的碳原子一起表示可取代的茚满基,环戊烯酰基或环戊烯基,n表示0、1或2,具有对抗害虫,特别是昆虫和螨类的有利特性。此外,描述了制备式I化合物的方法。

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