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POLYETHERAMINE OR POLYETHERAMINE DERIVATIVE FUELS FOR COMBUSTION ENGINES

机译:燃烧发动机的聚丙烯酰胺或聚丙烯酰胺衍生物

摘要

Fuels for spark ignition engines, which fuels contain small amounts of a polyether amine and/or polyether amine derivative of the general formula …IMAGE… in which R1 is a phenol- or alkylphenol-polyether radical of the general formula …IMAGE… or a cyclohexyl- or alkylcyclohexyl-polyether radical of the general formula …IMAGE… R2 and R3 may be identical or different and are hydrogen, the phenol- or alkylphenol-polyether radical (IIIa), the cyclohexyl- or alkylcyclohexyl-polyether radical (IIIb), the acyl radical of a carboxylic acid having 2 to 24 carbon atoms or the hydroxyalkyl radical of the general formula …IMAGE… or R2 is an alkyl radical having 1 to 20 carbon atoms and R3 is hydrogen, the phenol- or alkylphenol-polyether radical (IIIa), the cyclohexyl- or alkylcyclohexyl-polyether radical (IIIb), the acyl radical of a carboxylic acid having 2 to 24 carbon atoms or the hydroxyalkyl radical (IV), R4 is the carboxylate radical of a carboxylic acid having 2 to 24 carbon atoms, R5, R6 and R7 may be identical or different and are hydrogen or a hydrocarbon radical having 1 to 30 carbon atoms, R8 is a polyether chain comprising alkene oxides having 2 to 8 carbon atoms or mixtures of these alkene oxides having 2 to 100 alkene oxide units in the chain, and R9 is hydrogen or a hydrocarbon radical having 1 to 6 carbon atoms, and m is the numbers 0 to 5, the mean molecular weight Mn of the polyether amines or polyether amine derivatives (I) or (II) being 500 to 8000, and the polyether amines or the parent polyether amines to the polyether amine derivatives being prepared by amination of phenol- or alkylphenol-polyethers of the general formula …IMAGE… or of cyclohexyl- or alkylcyclohexyl-polyethers of the general formula …IMAGE… in which R5, R6, R7 and R8 are as defined above, using ammonia or primary amines. …??The novel polyether amines and their derivatives have an improved valve-cleaning action.
机译:用于火花点火发动机的燃料,该燃料包含少量通式为... ...的聚醚胺和/或聚醚胺衍生物,其中R <1>为通式为...的酚或烷基酚-聚醚基... <IMAGE>…或通式…<IMAGE>…的环己基-或烷基环己基-聚醚基团。R 2和R 3可以相同或不同,且为氢,酚或烷基酚-聚醚基(IIIa)。 ),环己基或烷基环己基-聚醚基团(IIIb),具有2至24个碳原子的羧酸的酰基基团或通式... ...或R 2的羟烷基基团为具有碳原子数为1至20的R 3为氢,苯酚或烷基苯酚聚醚基团(IIIa),环己基或烷基环己基聚醚基团(IIIb),具有2至24个碳原子的羧酸的酰基基团或羟基烷基基团(IV),R 4是具有2至24个碳原子的羧酸的羧酸根基团碳原子,R 5,R 6和R 7可以相同或不同,并且是氢或具有1至30个碳原子的烃基,R 8是包含具有2至3个碳原子的环氧烷烃的聚醚链。 8个碳原子或这些在链中具有2至100个环氧烷单元的环氧烷烃的混合物,R 9为氢或具有1至6个碳原子的烃基,m为0至5,平均分子数聚醚胺或聚醚胺衍生物(I)或(II)的重量M n为500至8000,并且聚醚胺或母体聚醚胺相对于聚醚胺衍生物的制备是通过通常的苯酚或烷基苯酚-聚醚的胺化来制备的通式………的式……或环己基或烷基环己基聚醚,其中R 5,R 6,R 7和R 8如上定义,使用氨或伯胺。 ………新型聚醚胺及其衍生物具有改进的阀门清洁作用。

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