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NON OXIDE SINTERED BODY HAVING IMPROVED WORKABILITY AND SYSTEM USING THE SAME

机译:具有改善的可加工性的非氧化物烧结体和使用该烧结体的系统

摘要

PURPOSE:To improve workability by sintering after mixing a prescribed molar ratio of a compound of metal element having specified ionic radius and a nonoxide ceramic. CONSTITUTION:Into the nonoxide ceramic incorporating 90vol.% of more than one kinds of silicon nitride, silicon carbide and zirconium boride consisting of elements each having 0.08nm ionic radius, for example, a fluoride, carbonate, nitrate, chloride, bromide, iodide or acetate of a metal element having 0.14nm ionic radius such as Ba, Rb or Cs and a compound decomposing below sintering temp. of sintered body to form metallic ions blended as 0.1-5mol% against the total sintered body. This blend is mixed, and after molding and sintering at a prescribed condition, a nonoxide sintered body having a structure in which the metallic ions exist at the boundary phase of the sintering body, a triple boundary point of the boundary phase and deposited material or the whole or a part of the boundary face. This sintered body is exemplified by the pressure cooker test in the condition, at 121 deg.C, 2 atm., 100% relative humidity lasting for 100hrs. and the weight difference per unit area of the sintered body by the test is 10-3g/cm2.
机译:目的:通过混合规定摩尔比的具有特定离子半径的金属元素的化合物和非氧化物陶瓷后进行烧结,以提高可加工性。组成:向非氧化物陶瓷中掺入> 90vol。%的一种以上氮化硅,碳化硅和硼化锆,其中每种元素的离子半径均小于0.08nm,例如氟化物,碳酸盐,硝酸盐,氯化物,溴化物,离子半径> 0.14nm的金属元素(例如Ba,Rb或Cs)的碘化物或乙酸盐,以及在烧结温度以下分解的化合物。烧结体的重量百分比,以形成相对于整个烧结体为0.1-5mol%的金属离子。将该混合物混合,并在规定条件下成型和烧结之后,形成具有在烧结体的边界相,边界相和沉积物的三重边界点存在金属离子的结构的非氧化物烧结体。整个或部分边界面。该烧结体通过在121℃,2个大气压,100%相对湿度下持续100小时的条件下的压力锅试验来举例说明。该试验的烧结体的每单位面积的重量差为<10 -3 g / cm 2。

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